Much of the fascination of pottery making centers
in the glaze. At one time a great deal of
mystery appeared to surround the composition and
use of glazes, but if one will take the trouble to learn,
much of this may be dispelled. Some knowledge of
chemistry is desirable if an understanding of the
theory of glaze-making is to be acquired, but a good
deal may be learned even without this knowledge.
Only such simple instruction as can be assimilated by
ordinary intelligence will be attempted here, as an
exhaustive treatment of the subject would be long and
tedious.
It is possible to purchase glazes ready for use[J] but
the true craftsman will not be satisfied until he can
prepare his own.
Glazes[K] belong to a class of chemical compounds
known as silicates; that is, they have silica as the
characteristic ingredient. Clear glazes are compound
silicates of lead, zinc, lime, potassium, sodium, aluminum
and boron. Matt glazes are characterized by
certain of these ingredients being present in excess;
and stanniferous or tin glazes are, as the name implies,
rendered opaque by the use of oxide of tin.
The commonest type of glaze is that which is made
from ready prepared, commercial substances. These
are called raw glazes as being made from raw materials
or materials which need no preparation.
It is possible to mix a glaze in a druggist's mortar
by hand, using fine sieves, but if the best results are
to be secured, a small mill must be used for grinding.
The best form of mill is the ball mill or jar mill.
This consists of a porcelain jar which is set in a
frame and made to revolve upon its axis in a horizontal
position. It is about half filled with porcelain
balls and these as they roll against each other perform
the grinding. These mills may be purchased ready
for use, either as a single jar to be worked by hand
or a battery of two or more revolved by power.[L]
A good pair of scales is a necessity and it will be
found convenient to use metric weights which need
no calculation into pounds and ounces. Suspended
scales are not as easy to use as the form known as
counter scales or balances. They should have movable
pans which are usually nickel plated. Upon these
the materials can be placed direct without the use of
pieces of paper, which are always troublesome and inaccurate.
There should be a graduated bar on the front
for the adjustment of weights of five grams and under.
This avoids the use of small weights which are
always being mislaid and lost. Dealers in chemical
supplies keep these scales in stock and the cost is
about eight dollars. A set of weights must also be
procured from one hundred grams to five grams inclusive.
These need not be of the accurate adjustment
which are used in analysis. A good inexpensive grade
is sufficient.
The ingredients for glazes are given in the following
list:
| Commercial Name | Chemical Name | Symbol or Formula | Equivalent Weight |
| White Lead | Lead Carbonate | Pb(OH)2 2PbCO3 | 258 |
| Zinc Oxide | Zinc Oxide | ZnO | 81 |
| Soda Ash | Sodium Carbonate | Na2CO3 | 106 |
| Niter | Potassium Nitrate | KNO3 | 202 |
| Whiting | Calcium Carbonate (Carbonate of Lime) | CaCO3 | 100 |
| Feldspar | Orthoclase | K2O, Al2O3, 6SiO2 | 557 |
| Kaolin or China Clay | Aluminum Silicate | Al2O3, 2SiO2, 2H2O | 258 |
| Flint | Silica | SiO2 | 60 |
| Borax | Sodium di Borate | Na2B4O710H2O | 382 |
| Boric Acid | Boric Acid | B2O33H2O | 124 |
For coloring, the following metallic oxides are used:
| Color | Chemical Name | Symbol or Formula | Equivalent Weight |
| Blue | Cobalt Oxide | CoO | 80 |
| Blue and Green | Copper Oxide | CuO | 79 |
| Gray and Brown | Nickel Oxide | NiO | 75 |
| Brown and Yellow | Iron Oxide | Fe2O3 | 160 |
| Brown | Manganese Carbonate | MnCO3 | 115 |
Under-glaze colors may also be used for coloring
glazes, the color being ground with the glaze batch.
It is not absolutely necessary to commit the formula
and equivalent weight to memory. They will soon be
remembered as use becomes second nature.
A glaze is usually expressed as the chemical formula.
In this there are three divisions given, each of which
expresses a distinct function. On the left hand are
the bases, the foundation of the glaze. These indicate
the type, such as lead glaze, a lime glaze, an
alkaline glaze, etc. All glazes being silicates, this is
the usual way of distinguishing them. In the center
are the alumina and boron oxide. These regulate the
behavior of the glaze in the fire. They make it viscous
or sluggish as it melts and prevent a too rapid flow.
The alumina is infusible, the boron is fusible, but
boron cannot be used in a raw glaze for reasons to
be presently explained. At the right stands the silica,
the dominating factor with which all the other ingredients
combine, and which controls the behavior of
the whole as regards the fitting of the glaze to the
body.
The very simplest form of glaze is a bisilicate of
lead, represented by the formula PbO, SiO2, or one
equivalent of lead oxide and one of silica. The term
"equivalent" means that the mixture is calculated,
not upon the actual weight of a substance but upon its
equivalent or unit weight. Thus the equivalent weight
of lead oxide, PbO, being 222, in order to produce the
formula in actual weight 222 grams or pounds must
be weighed out. It does not matter what weights are
used so long as they are the same for all.
In like manner the equivalent weight of silica is 60
and as flint is pure silica, the formula PbO, SiO2
would be produced by weighing—
| Litharge or Lead Oxide | 222 parts |
| Flint or Silica | 60 parts |
Litharge is not, however, a convenient substance to
use. It is very heavy and does not mix well in water.
The most usual substance for the introduction of lead
oxide is white lead. This is not lead oxide but it
changes to lead oxide when burned. White lead bears
the formula Pb(OH)2, 2PbCO3, which, being dissected
is found to be 3PbO, H2O, 2CO2. H2O is
water and CO2 carbonic acid, both of which pass off
in burning. Both, however, are weighed when the
white lead is put on the scales and therefore the
equivalent weight of white lead is 258 and not 222.
The mixture for practical purposes then would be—
| White Lead | 258 parts |
| Flint | 60 parts |
Which, when ground and spread upon the ware would
be a very fusible glaze of a yellowish tone.
This was spoken of as a bisilicate of lead because
the measure of the silica, also called the acidity of a
glaze, is calculated upon the oxygen contained in the
base and the silica respectively. PbO contains one
molecule of oxygen, SiO2 contains two. Hence the
relationship of the oxygen in the base to the oxygen
in the silica is as one to two. This is called simply
the "oxygen ratio" and is of great importance in determining
the behavior of a glaze. While this simple
bisilicate of lead will be a glaze under certain conditions
it is found to possess two faults. 1. It is too
fluid under fire. The glaze will run down a vertical
surface and leave the upper edge of the piece bare.
2. If subjected to a long slow fire it will lose its gloss
and become devitrified. This devitrification is often
seen in commercial work and appears as a dull scum
in patches and around the edges of the ware. It is,
in fact, a crystallization of the silica which separates
out, as salt does from an evaporated brine. Both these
faults may be corrected by the addition of a little
alumina to the glaze. A whole equivalent of alumina
would be too much, in fact it is found in practice that
.2 equivalent is sufficient for most lowfire glazes. In
order to maintain the oxygen ratio and to keep the
glaze as a bisilicate the silica content must be raised.
Alumina contains three molecules of oxygen so that
the total amount of alumina is multiplied by three and
the silica brought to the equal point thus:
PbO, .2Al2O3, 1.6SiO2
The amount of silica required in any bisilicate glaze
may be found by the following equation:
SiO2 = 2(3Al2O3 + 1) / 2
Thus if the alumina content were .25 equivalent this
would be expressed:
SiO2 = 2(.75 + 1) / 2
Or—
SiO2 = 3.50 / 2 = 1.75 equivalent
Now in order to produce this as a mixture it would
be possible to introduce the alumina in the pure state,
but pure alumina is expensive and clay which contains
alumina is cheap so that clay is generally used to supply
the alumina. Clay, however, contains silica as well,
and therefore allowance must be made for this. On
referring to the formula for kaolin, the purest form
of clay, Al2O3, 2SiO2, 2H2O, it will be seen that there
is twice as much silica present in equivalence as there
is alumina and therefore .2 kaolin will contain .2Al2O3
and 4SiO2. Subtracting, then, the 4SiO2 from the
1.6SiO2 needed there will be 1.2 left to be supplied in
the form of flint. The mixture therefore is—
| White Lead | 1.0 × 258 = 258 |
| Kaolin | .2 × 258 = 51.6 |
| Flint | 1.2 × 60 = 72 |
This is a glaze of the same character as that first
given except that it no longer flows unduly from the
higher places nor will it devitrify in a long-continued
fire. The alumina will have counteracted both these evils.
A glaze with only lead oxide as the base is not,
however, desirable for general use. The color is yellowish
and the lead oxide is apt to destroy the hue
of any colors which are used with it. The available
bases may be classified under three heads. 1. The
metallic oxides, lead and zinc oxides. 2. The alkaline
earths, the oxides of calcium and barium. 3. The
alkalies, potash and soda. Barium oxide is not often
used and soda cannot be used in raw glazes because
there is no convenient substance which contains it.
As glazes are always ground in water only insoluble
ingredients can be employed without preparation. Potash
is found in feldspar which is insoluble and while
there is a so-called soda feldspar it can rarely be obtained
of sufficient purity.
In arranging the bases with which to compose a
glaze it is desirable to use one at least from each
class, but it must be borne in mind that however many
bases are introduced the total must always be unity.
This unit is, for the sake of brevity, described as RO.
For example the following groups may be set forth:
| 1. | PbO Lead Oxide | .7 |
| | CaO Calcium Oxide | .3 |
| | | —— |
| | RO | 1.0 |
| 2. | PbO | .6 |
| | CaO | .4 |
| | | —— |
| | RO | 1.0 |
| 3. | PbO Lead Oxide | .5 |
| | ZnO Zinc Oxide | .2 |
| | CaO Calcium Oxide | .3 |
| | | —— |
| | RO | 1.0 |
| 4. | PbO | .6 |
| | ZnO | .1 |
| | CaO | .3 |
| | | —— |
| | RO | 1.0 |
| 5. | PbO Lead Oxide | .6 |
| | CaO Calcium Oxide | .3 |
| | K2O Potassium Oxide | .1 |
| | | —— |
| | RO | 1.0 |
| 6. | PbO | .50 |
| | CaO | .35 |
| | K2O | .15 |
| | | —— |
| | RO | 1.00 |
| 7. | PbO Lead Oxide | .45 |
| | ZnO Zinc Oxide | .10 |
| | CaO Calcium Oxide | .30 |
| | K2O Potassium Oxide | .15 |
| | | —— |
| | RO | 1.00 |
| 8. | PbO | .35 |
| | ZnO | .15 |
| | CaO | .35 |
| | K2O | .15 |
| | | —— |
| | RO | 1.00 |
The reason for the unit rule is that if one formula
is to be compared with another there must be a uniform
basis upon which to work and, furthermore, it makes
no difference whether the silica combines with one,
two, three, or four bases, the chemical action is the
same and, so long as the sum of the bases is kept at
unity, the same amount of silica will be required.
If two glazes be taken as an illustration this will be
made clear:
| PbO | .6 | } |
| CaO | .4 | } | Al2O3 | .2 | SiO2 | 1.6 |
| | —— | } |
| | 1.0 | } |
| | |
| PbO | .46 | } |
| ZnO | .12 | } |
| CaO | .28 | } | Al2O3 | .2 | SiO2 | 1.6 |
| K2O | .14 | } |
| | —— | } |
| | 1.00 | } |
Both of these formulae are bisilicates and each being
properly fired, will stand, without crazing, on the
same body.
The use of the formula is to give an insight into
the composition of the melted glaze. It takes no account
of volatile ingredients or losses in the fire but
for this very reason it must be translated into the
substances to be weighed before use can be made of it.
Of the ingredients given on pages 142, 143, some
contain but one item of the formula, others contain
several, as in the case of kaolin already cited. Feldspar,
of the variety known as potash feldspar and
named by mineralogists, "orthoclase," is a very useful
ingredient in raw glazes, being, in fact, almost the
only source of potash. The formula, page 142, shows
that a molecule or equivalent of feldspar contains one
molecule of potash K2O, one of alumina Al2O3, and
six of silica SiO2. This fact is taken into account in
calculating the mixture or batch weight.
Base No. 5 (page 148), is as follows:
And this made up into a bisilicate glaze would be:
| PbO | .6 | } |
| CaO | .3 | } | Al2O3 | .2 | SiO2 | 1.6 |
| K2O | .1 | } |
| | —— | } |
| | 1.0 | } |
These items are extended in a horizontal line, a
space being left on one side for the list of ingredients.
| | PbO | CaO | K2O | Al2O3 | SiO2 |
| | .6 | .3 | .1 | .2 | 1.6 |
| Addition | .6 | | | | | White Lead | .6 |
| Subtraction | .0 | .3 | .1 | .2 | 1.6 |
| Addition | | .3 | | | | Whiting | .3 |
| Subtraction | | .0 | .1 | .2 | 1.6 |
| Addition | | | .1 | .1 | .6 | Feldspar | .1 |
| Subtraction | | | .0 | .1 | 1.0 |
| Addition | | | | .1 | .2 | Kaolin | .1 |
| Subtraction | | | | .0 | .8 |
| Addition | | | | | .8 | Flint | .8 |
| Subtraction | | | | | .0 | | |
Each item is thus disposed of until the list is complete.
These figures are, however, given in equivalents
and each must be multiplied by the equivalent
weight of the substance used.
| White Lead | .6 × 258 = | 154.8 | parts by weight |
| Whiting (calcium carbonate) | .3 × 100 = | 30.0 | " " " |
| Feldspar | .1 × 557 = | 55.7 | " " " |
| Kaolin | .1 × 258 = | 25.8 | " " " |
| Flint | .8 × 60 = | 48.0 | " " " |
| | | —— | |
| | | 314.3 | Batch of Glaze |
These amounts are weighed out in grams, put upon
the mill with half a pint of water, and ground for
about an hour. When taken off, the jar and porcelain
balls are washed with plenty of water and the washings
saved. The glaze, thus diluted, is strained through a
lawn of 120 mesh and laid aside to settle. The clear
water is then siphoned or poured off and the glaze
is ready for use.
For glazing the glaze should be as thick as cream.
A finger dipped into it should show a white coating
which cannot be shaken off. The pottery to be glazed
should be first soaked in clean water until all absorption
has ceased. It is then wiped dry and plunged
into the glaze bath, or, if the piece be large, the
glaze may be poured over it. The piece is gently
shaken to distribute the glaze evenly and it is then set
aside to dry. Before glazing a piece everything should
be prepared. A stilt or support upon which to set the
wet glazed pottery, and a bowl of water in which to
wash the fingers so as to save all the glaze. It will
be found best to glaze the inside of the piece first.
It should then be well shaken to remove as much glaze
as possible before beginning the outside. A thick
glaze inside is almost sure to run down to the bottom
where it will form a pool and perhaps burst the piece.
Before firing, the bottom of the pottery should be
carefully trimmed. Any excess of glaze is removed
and the point of contact with the table is sponged
clean. Then, when the piece is set in the kiln the
bottom will not be inclined to stick.
The texture of the matt glaze is always pleasing
and the artist is not content unless at least
some of his work can be finished in this way.
Matt glazes are not underfired glazes nor are they
deadened by acid or sand blast. They are produced
in two ways. First, by an excess of alumina which
is believed to cause the formation of certain compounds
in the glaze, and, second, by an excess of
silica which produces a devitrified surface. It was
mentioned in the last chapter that a glaze free from
alumina will devitrify or become dull. This is undesirable
when a glaze is intended to be brilliant but it
may be controlled and turned to advantage in the
production of a certain type of matt. The successful
preparation of this silica matt is extremely difficult.
In fact, in the studio kiln it is almost impossible.
These small kilns are apt to cool with great rapidity
whereas, in order to produce the silica matt the kiln
must be cooled very slowly, hours and even days of
cooling being sometimes necessary.
The alumina matt is more simple and its texture
is quite satisfactory, being, in the opinion of some,
the more pleasing of the two.
It was mentioned in the last chapter that the best
bright glazes for low temperature work are bisilicates,
having an oxygen ratio of 1:2. The alumina matt has
an oxygen ratio of about 3:4. This is secured in the
following manner. The RO content may consist of
any of the bases used in bright glazes, the proportion
of each being adjusted in accordance with the desired
point of fusion. The alumina content is rather higher
than in a bright glaze and should not fall much below
.3 equivalent, .35 equivalent is even better. The silica
is adjusted in accordance with the following equation:
SiO2 = 3(3Al2O3 + 1) / 4
Now if the alumina content be placed at .35 equivalent
this would work out:
SiO2 = 3(1.05 + 1) / 4
Or:
SiO2 = 6.15 / 4 = 1.5375
But as such a complete fraction is not necessary it
may be stated as 1.54 equivalent. The formula would
therefore be:
RO, Al2O3 .35, SiO2 1.54
The RO content should not be too fusible. Lead
oxide is desirable up to about .5 equivalent and it is
an advantage to use feldspar so that K2O may be
introduced. Calcium oxide is also good but zinc oxide
must be used sparingly as it is apt to suffer if overfired.
The high content of alumina necessitates a good deal
of clay and as this, if used raw, would make the
glaze too plastic and cause it to crack, it is best to
calcine a part of it, thus removing the combined water
and changing the equivalent weight from 258 to 222.
The calculation will then proceed as in the case of
a bright glaze.
| PbO | .50 | } |
| CaO | .35 | } | Al2O3 | .35 | SiO2 | 1.54 |
| K2O | .15 | } |
| | —— | } |
| | 1.0 | } |
| | PbO | CaO | K2O | Al2O3 | SiO2 |
| | .50 | .35 | .15 | .35 | 1.54 |
| Addition | .50 | | | | | White Lead | .50 × 258 = 129 |
| Subtraction | .0 | .35 | .15 | .35 | 1.54 |
| Addition | | .35 | | | | Whiting | .35 × 100 = 35 |
| Subtraction | | .0 | .15 | .35 | 1.54 |
| Addition | | | .15 | .15 | .90 | Feldspar | .15 × 557 = 83 |
| Subtraction | | | .0 | .20 | .64 |
| Addition | | | | .15 | .30 | Calcined Kaolin | .15 × 222 = 33 |
| Subtraction | | | | .05 | .34 |
| Addition | | | | .05 | .10 | Kaolin | .05 × 258 = 13 |
| Subtraction | | | | .0 | .24 |
| Addition | | | | | .24 | Flint | .24 × 60 = 14 |
| Subtraction | | | | | .0 |
The mix, therefore, is:
| White Lead | 129 grams |
| Whiting | 35 " |
| Feldspar | 83 " |
| Calcined Kaolin | 33 " |
| Kaolin | 13 " |
| Flint | 14 " |
This will give a silky matt glaze, nearly white, maturing
at about cone 1. If a lower fusing point is
desired the white lead may be increased at the expense
of the whiting or if the glaze prove too fusible
the reverse will correct it. The flint may be omitted
without damage.
The grinding of a matt glaze is of great importance.
It is better to have it too coarse than too fine. Grinding
for one hour on the ball mill should be ample and
if the glaze be then strained through 120 mesh lawn
all coarse particles will be arrested. A glaze that is
too fine will crack and peel off or will curl up in the kiln.
More than half the success of matt glazes lies in
the using. It is necessary that the coating of glaze
be very thick or the true texture will not be developed.
When the glaze is taken from the mill plenty of water
may be used in order to wash the apparatus clean and
to save all the glaze. This is set aside in a deep bowl
to settle. After some hours the clear water is carefully
drawn off with a siphon.
Half an ounce of gum tragacanth is put to soak
in a quart of clean water. After twelve hours the
gum will have swollen to a jelly-like mass. This is
now worked vigorously with a Dover egg-beater or
in a Christy mixer and again set aside. After another
twelve hours the operation is repeated and the
solution is a clear syrup of the consistency of thin
molasses. A drop or two of carbolic acid or other
germicide should be added to prevent decomposition.
This mucilage should be prepared in advance. To the
glaze batch from which the water has been removed
a tablespoonful of the mucilage is added. If more
of the glaze than the single batch has been weighed
out then more mucilage will be necessary. The mixture
is to be stirred very thoroughly and it will be
found to thicken under the hand. It must be very
much thicker than the bright glaze. In fact, the thicker
it is the better, only that it must flow sufficiently
so that the pottery may be covered with a smooth
coating, avoiding lumps. Matt glazes do not correct
their own faults in the kiln as bright glazes do. Every
finger mark will show and, consequently, the glazing
must be done with the greatest care. The process is
the same as that described for bright glazes, except
that as much glaze as possible is left on the ware.
No more shaking should be done than will suffice to
secure a smooth coating. It is well to place the pieces
upside down to dry.
For the inside of the pieces a matt glaze may be
used or a thin coat of clear glaze at the pleasure of
the worker. If the latter, care must be taken that
none of the inside glaze is allowed to run over the
edge.
In firing, the pottery is sometimes placed on a stilt
but this is not absolutely necessary. For a support
a flat piece of burned clay may be used and this
should be covered with an infusible wash to prevent
any possibility of sticking. Equal parts of kaolin and
flint make a good wash. The wash is worked up with
water into a slip and applied with an ordinary brush.
Fritted glazes, like raw glazes, are clear and
brilliant and for most purposes the latter will
suffice. Since, however, the aim of this work is to
give as complete information as may be the fritted
glaze will not be omitted.
A fritt is a melt or compounded glass and the purpose
of it is to permit the use of certain ingredients
which are not available in the raw state. As glazes
are ground in water it is essential that the substances
used be insoluble. This condition would prohibit advantage
being taken of borax, boric acid, and soda
ash, if it were not for the possibility of rendering
these insoluble by the operation of fritting.
The following is an example of a fritted glaze:
| PbO Lead Oxide | .30 | } |
| ZnO Zinc Oxide | .15 | } | Al2O3 Alumina .15 | } |
| CaO Lime | .25 | } | B2O3 Boric Acid .40 | } | SiO2 Silica 2.65 |
| Na2O Soda | .20 | } |
| K2O Potash | .10 | } |
This will be produced in accordance with the usual
calculation by the mix:
| White Lead | .3 × 258 | = | 77 |
| Zinc Oxide | .15 × 81 | = | 12 |
| Whiting | .25 × 100 | = | 25 |
| Borax | .20 × 382 | = | 76 |
| Feldspar | .10 × 557 | = | 56 |
| Kaolin | .05 × 258 | = | 13 |
| Flint | 1.95 × 60 | = | 117 |
The borax contains the required amount of both
soda and boric acid and the potash is supplied by the
feldspar. Borax, being soluble, must be melted with
certain other ingredients into an insoluble glass, thus:
| Fritt: |
| Borax | 76 x 2 = | 152 |
| Whiting | 25 x 2 = | 50 |
| Feldspar | 30 x 2 = | 60 |
| Flint | 50 x 2 = | 100 |
| | | —— |
| | | 362 |
These ingredients are weighed out in double quantity
to guard against loss in melting and are fused
either in the kiln or in a special furnace. A good
fritting furnace is the No. 15, made by the Buffalo
Dental Manufacturing Company. The charge is put
into a plumbago crucible and when melted is poured
out into water. This breaks up the fritt and renders
it easy to grind. A similar crucible may be used in
the kiln but as the fritt becomes very hard when cold
and a crucible must be broken each time, the furnace
method is better. If the fritt as given prove too sluggish
to pour freely, the feldspar may be omitted, being
added, of course, to the glaze mix. The melted
weight of the fritt must now be calculated.
Borax contains in each equivalent 180 parts water.
Whiting contains in each equivalent 44 parts carbonic
acid. Both water and carbonic acid pass off in the
melting, thus the 76 parts of borax will be reduced
in weight to 40 parts, and the 25 parts of whiting
will be reduced to 14 parts. Spar and flint undergo
no loss. The fritt after melting will therefore be:
| Borax | 40 |
| Whiting | 14 |
| Spar | 30 |
| Flint | 50 |
| | —— |
| | 134 |
And the final mix for the glaze will be:
| Fritt | 134 parts |
| White Lead | 77 " |
| Zinc Oxide | 12 " |
| Feldspar | 26 " |
| Kaolin | 13 " |
| Flint | 67 " |
This is ground on the mill as already directed and
is ready for use.
Fritted glazes are better than raw glazes for certain
classes of ware. They are usually whiter and
less easily scratched. They are, moreover, better for
use with underglaze colors and are, as a rule, more
easily melted. It is never necessary to make a fritt
for the preparation of matt glazes.
While the purpose of this work is not so much
to put ready-made materials into the hands of
the craftsman as to enable him to work out his own
plans, it is recognized that there are some workers
who lack the training and even the patience to do this.
For these, the following recipes are given, but with
the proviso that no recipe can be regarded as perfect
for all conditions. Just as an untrained cook can
spoil a dinner even when surrounded by cookery
books, so the best of recipes will fail when unskillfully
treated. One must be prepared to recognize the faults
which are sure to develop and to correct them in an
intelligent manner. The previous chapters should
therefore be carefully studied, not alone for the information
but because "the joy of the working" depends
greatly upon the knowledge one has of the
operations involved and a modest confidence in one's
own powers.
1. Bright raw glaze.
| Cone .06 |
| PbO | .60 | } |
| CaO | .25 | } | Al2O3 | .15 | SiO2 | 1.45 |
| K2O | .15 | } |
| Mix: |
| White Lead | 155 |
| Whiting | 25 |
| Feldspar | 55.7 |
| Kaolin | 13 |
| Flint | 45 |
| Grind, with one-half pint of water, for one hour. |
2. Bright raw glaze.
| Cone 1 |
| PbO | .45 | } |
| ZnO | .15 | } | Al2O3 .20 | SiO2 | 1.60 |
| CaO | .25 | } |
| K2O | .15 | } |
| Mix: |
| White Lead | 116 |
| Whiting | 25 |
| Zinc Oxide | 12 |
| Feldspar | 83 |
| Kaolin | 13 |
| Flint | 36 |
3. Bright fritted glaze.
| Cone .02 |
| PbO | .25 | } |
| ZnO | .15 | } | Al2O3 .15 | } |
| CaO | .30 | } | B2O3 .30 | } | SiO2 2.35 |
| Na2O | .20 | } |
| K2O | .10 | } |
| Mix: |
| Fritt | | Glaze | |
| Borax | 114 | Fritt | 117 |
| Whiting | 60 | White Lead | 64 |
| Soda Ash | 10 | Zinc Oxide | 12 |
| Spar | 56 | Spar | 28 |
| Flint | 78 | Kaolin | 13 |
| | | Flint | 60 |
| Grind as before. |
4. Matt glaze.
| Cone .02 |
| PbO | .50 | } |
| CaO | .30 | } | Al2O3 .34 | SiO2 1.48 |
| K2O | .20 | } |
| Mix: |
| White Lead | 129 |
| Whiting | 30 |
| Spar | 111 |
| Calcined Kaolin | 22 |
| Kaolin | 11 |
5. Matt glaze.
| Cone 7 |
| CaO | .75 | } | Al2O3 .55 | SiO2 2.10 |
| K2O | .25 | } |
| Mix: |
| Feldspar | 139 |
| Whiting | 75 |
| Calcined Kaolin | 55 |
| Kaolin | 13 |
For colored glazes add to any of the above:
| Blue: |
| | Cobalt Oxide | 3 parts |
| Slate blue: |
| | Cobalt Oxide | 3 parts |
| | Nickel Oxide | 1 part |
| Warm blue: |
| | Cobalt Oxide | 2 parts |
| | Iron Oxide | 1 part |
| Green: |
| | Copper Oxide | 8 parts |
| Blue green: |
| | Copper Oxide | 8 parts |
| | Cobalt Oxide | 1 part |
| Cool green: |
| | Copper Oxide | 8 parts |
| | Cobalt Oxide | 1 part |
| | Nickel Oxide | 2 parts |
| Olive green: |
| | Copper Oxide | 6 parts |
| | Iron Oxide | 4 parts |
| Orange brown: |
| | Iron Oxide | 8 parts |
| Red brown: |
| | Iron Oxide | 8 parts |
| | Chrome Oxide | 1 part |
| | Zinc Oxide | 3 parts |
| Yellow: |
| | Uranium Oxide | 3 parts |
The coloring oxides should be weighed out and
ground with the glaze. Any of the colors may be
mixed together in order to modify the hue obtained
or the amount of each coloring oxide may be varied
to give a stronger or weaker value.
Opaque tin enamel.
| Cone .02 |
| PbO | .40 | } |
| CaO | .25 | } | | { | SiO2 | 1.75 |
| K2O | .20 | } | Al2O3 .25 | { | SnO2 .30 |
| ZnO | .15 | } |
| Mixture: |
| | White Lead | 103 |
| | Whiting | 25 |
| | Feldspar | 111 |
| | Zinc Oxide | 12 |
| | Kaolin | 13 |
| | Flint | 27 |
| | Tin Oxide | 45 |
| Grind, with one-half pint of water, for 45 minutes. |
While it may chance that body and glaze and
fire are so adjusted that faults do not develop,
this state of things is rare. Besides, it is always possible
that an occasional trouble may arise, hence it
will be well to recount a few of the commonest defects
with the method of cure. A cure is not necessarily
specific. There may be a complication of causes but
the remedy indicates the line along which relief will
be found.
1. Crazing. Fine cracks appear in the glaze but
do not penetrate the body. There are many causes.
The body may be underfired or overfired. In the former
case the crazing does not always appear at once
and it grows worse upon standing. In the latter case
the glaze is found to be crazed when taken from the
kiln and it does not extend even after long standing.
The glaze may be underfired. In this case the lines
of the crack are broken and irregular, one often
changing its direction without meeting another crack.
In all these cases the remedy is obvious.
Crazing also occurs when both body and glaze are
correctly fired but there is an inherent disagreement in
expansion. In such a case a little flint added either
to the body or to the glaze will tend to cure the trouble
but it must be remembered that the addition of flint
to the glaze is apt to render it less fusible and therefore
while one craze may be cured another may be
caused. The addition of flint to the body is the simplest
remedy.
2. Shivering or peeling. This is the reverse of
crazing and is caused by the glaze being too large
for the body. It almost always appears immediately
the ware is cooled. The symptoms are that edges or
convex surfaces are pushed off and even the ware
itself is shattered. The remedy is to decrease the
flint in either body or glaze.
3. Blistering. Glazes, both bright and matt, are apt
to develop blisters at times. These may be yet unbroken
when the kiln is opened or they may have
melted down to a small crater, a ring with a depression
in the center. The cause of this fault is usually
to be found in the body. All clays contain sulphur
and when a clay is aged this develops an acid which
rises to the surface of the ware when dried and causes
a scum. The glaze attacks this sulphate scum and a
gas is generated which boils out and causes the blisters.
If old clay blisters and new clay does not it
may be regarded as certain that this is the cause. A
little barium carbonate added to the clay will help to
effect a cure. About one per cent. is usually enough.
Clay so treated, however, must not be used in plaster
molds as the barium attacks the plaster. If the cause
be not found in the clay it may exist in the glaze itself.
Some glaze ingredients contain impurities in the form
of sulphates and these will cause blisters.
4. The glaze flows, leaving bare places. It is too
fluid, add a little clay and flint.
5. A matt glaze burns to a bright surface. Matt
glazes must be used in a very thick coat. If too thin
they will inevitably brighten. The fire may be too
high. The fire may be "reducing," that is, with insufficient
air.
6. The glaze crawls or rolls up in lumps. Notice
whether the glaze is cracked before burning. If so
it will surely crawl. Too fine grinding is usually the
cause of this trouble. Too much clay in the glaze
may cause it, or a too porous body. A body which is
underfired will almost certainly cause the glaze to
crawl.
7. Pinholes appear in the glaze when cool. Too
rapid cooling is the cause.
The glory of the Persian and Egyptian blue is
too alluring for potters to withstand. Though
the pursuit of this glory leads one into all kinds of
disasters and failures, the avenues of research that
it opens add unending fascination to the study. Even
one beautiful glowing pot out of twenty or more efforts
is a stimulating achievement though it should
not be thought that this is the usual proportion.
It is a continual source of astonishment that with
a slight variation of glaze formula a positive green
will swim into a vibrating blue. The addition or substitution
of one substance or another in the glaze mix
may be the key to an unexpected transformation and
may give the potter a new palette of color.
The clay body has a very positive effect on alkaline
glaze both in its composition and its color. This is
especially true under a transparent glaze where the
effect is considerable since the color of the glaze would
be modified by the red or buff clay showing through.
If, therefore, the object of the potter is to obtain
a brilliant "Persian" blue, a white clay body must be
composed or a white engobe applied over the buff or
red clay to hide the color.
The Persians and Egyptians used a coarse, sandy
body high in silica and covered the roughness of the
clay with a fine white engobe on which they painted
their decorations in various colors. The whole was
finally covered with the transparent alkaline glaze.
While the effect of colored clay under opaque glaze
is less pronounced, it still makes sufficient difference
to be considered.
The word engobe is French and refers to a thin
coating of clay, also called a slip, laid over a colored
body to change the color or over a coarse body to
give a finer texture.
The engobe is usually composed of china clay, flint,
and feldspar much as a white earthenware body is
constituted but with a larger content of flint. Ball
clay may also be used but the color is not so white.
The mixture of porcelain given on page forty will
make an engobe suitable for many clay bodies. If it
should crack on drying more flint should be added.
An engobe must, of course, be put upon the unburned
or green clay ware and this should be leather
hard, not dry. The body with the engobe may be
burned before glazing or the glaze may be put upon
the unburned ware and the whole subjected to one
fire only.
The ingredients in alkaline glazes are soda-ash,
whiting, feldspar, flint and oxide of tin. The following
is an example of a fritted glaze:
| Na2O | .60 | } |
| K2O | .10 | } Al2O3 .10 | SiO2 1.30 |
| CaO | .30 | } |
| |
| | Soda Ash | 64 |
| | Whiting | 30 |
| | Feldspar | 56 |
| | Flint | 42 |
The entire batch is fritted and ground in a ball
mill with the usual amount of water for fritt grinding,
adding a tablespoonful of gum tragacanth mucilage
to the batch after it is sieved. The glaze should be
the consistency of heavy cream when used.
It is also possible to use an alkaline glaze in the
raw or unfritted state. This necessitates grinding by
hand in a mortar, but great care must be taken to mix
the dry ingredients thoroughly before adding water
and to stir the glaze constantly while pouring in the
water, otherwise the soda-ash will cake and harden
and be very difficult to break up. A batch of glaze
can be ground by hand in fifteen or twenty minutes
if done vigorously. It is then put through a 120-mesh
sieve. The consistency is of importance. If too much
water has been added and the glaze has become thin,
it cannot be used successfully and should be discarded.
Unfritted alkaline glaze does not keep well when moist
but the ingredients can be ground dry and kept ready
to be moistened as needed.
The following is an example of an unfritted alkaline
glaze:
| Na2O | .59 | } |
| CaO | .21 | } | Al2O3 .20 | SiO2 1.6 |
| K2O | .20 | } |
| |
| | Soda Ash | 62 |
| | Whiting | 21 |
| | Feldspar | 111 |
| | Flint | 24 |
For color add the following oxides to a batch.
1. Egyptian blue, opaque—from 5 to 8 grams of
black oxide of copper—16 grams of oxide of tin.
2. Persian blue, opaque—from 8 to 10 grams of
black oxide of copper—16 grams of oxide of tin.
3. Sapphire blue—1 gram black oxide of cobalt.
4. Aubergine—9 grams black oxide of manganese.
The clear glaze without any coloring oxide can be
used over any of the colored glazes. This is sometimes
necessary when the colored glaze contains such
a large proportion of coloring oxide as to show black
on the surface.
The application of alkaline glaze is very important.
Any of the three methods of pouring, dipping, and
brushing can be employed. Brushing seems to give
the best results but the glaze must be put on thick, in
two or three coats, to give quality.
The firing is interesting and important because of
the varied effects it develops from the same formula.
The range of temperature is great, varying from cone
.05 to 1, developing the alkaline glaze according to
the result desired. If the biscuit is soft fired the color
will be more intense; if hard fired, the color will be
much lighter in value with a high sheen on the surface.
An unfritted alkaline glaze burned to .05 develops a
soft matt finish.
Where the color of a transparent Persian blue
comes out olive green, too little glaze has been used on
the piece or the buff of the clay has modified the
color. Bubbles mean undeveloped glaze or sulphur in
the clay or fuel. Black scum shows an excess of copper
in the batch, or reduction in the fire. Sand paper
surface proves too low firing or too thin a glaze.
If one desires to reproduce the underglaze Persian
decoration the black outlines may be drawn with a
black underglaze color mixed with clay. A little mucilage
must be added to secure smooth working. The
turquoise blue is copper oxide, the dark blue cobalt,
and the purple manganese. The oxides must be diluted
with white clay and used rather thin. The Rhodian
red is a finely ground red burning clay mixed with
a little flint. This red must be laid on quite thickly.
It will probably be found necessary to fire the painted
decoration to about cone .03 before glazing. The glaze
may be either quite clear or slightly tinted. Another
effect may be produced by using the black outline
alone under a peacock blue or turquoise glaze.
A great many modifications and additions to this
subject will suggest themselves to the potter as he
works, and a continual study of the masterpieces of
the Persians in the museums will prove the greatest
inspiration.