No one who is not familiar with the history of physical
science can appreciate how very modern are those
grand conceptions which add so much to the loftiness of
scientific studies; and, of the many who, on one of our
starlit nights, look up into the depths of space, and are
awed by the thoughts of that immensity which come
crowding upon the mind, there are few, I imagine, who
realize the fact that almost all the knowledge which
gives such great sublimity to that sight is the result of
comparatively recent scientific investigation; and that
the most elementary student can now gain conceptions of
the immensity of the universe of which the fathers of
astronomy never dreamed. And how very grand are
the familiar astronomical facts which the sight of the
starry heavens suggests!
Those brilliant points are all suns like the one which
forms the center of our system, and around which our
earth revolves; yet so inconceivably remote, that, although
moving through space with an incredible velocity,
they have not materially changed their relative
position since recorded observations began. Compared
with their distance, the distance of our own sun—92,000,000
miles—seems as nothing; yet how inconceivable
even that distance is when we endeavor to mete it out
with our terrestrial standards! For if, when Copernicus—the
great father of modern astronomy—died, in 1543,
just at the close of the Protestant Reformation, a messenger
had started for the sun, and traveled ever since
with the velocity of a railroad train—thirty miles an hour—he
would not yet have reached his destination!
Evidently, then, no standards, which, like our ordinary
measures, bear a simple or at least a conceivable
relation to the dimensions of our own bodies, can help us
to stretch a line in such a universe. We must seek for
some magnitude which is commensurate with these immensities
of space; and, in the wonderfully rapid motion
of light, astronomy furnishes us with a suitable standard.
By the eclipses of Jupiter's satellites the astronomers
have determined that this mysterious effluence reaches us
from the sun in eight minutes and a half, and therefore
must travel through space with the incredible velocity—shall
I dare to name it?—of 186,000 miles in a second of
time! Yet, inconceivably rapid as this motion is, capable
of girdling the earth nearly eight times in a single second,
the very nearest of the fixed stars, α Centauri, is so
remote that the light by which it will be seen in the
southern heavens to-night, near that magnificent constellation,
the Southern Cross, must have started on its
journey three years and a half ago. But this light comes
from merely the threshold of the stellar universe; and
the telescope reveals to us stars so distant that, had they
been blotted out of existence when history began, the
tidings of the event could not yet have reached the earth!
Compare now with these grand conceptions the popular
belief of only a few centuries back. Where we look
into the infinite depths, our Puritan forefathers saw
only a solid dome hemming in the earth and skies, and
through whose opened doors the rain descended. They
regarded the sun and moon merely as great luminaries
set in this firmament to rule the day and night, and to
their understandings the stars served no better purpose
than the spangles which glitter on the azure ceiling of
many a modern church. The great work of Copernicus,
"De Orbium Cœlestium Revolutionibus," which was
destined, ultimately, to overthrow the crude cosmography
which Christianity had inherited from Judaism, was not
published until just at the close of the author's life in
1543, the date before mentioned. The telescope, which
was required to fully convince the world of its previous
error, was not invented until more than half a century
later, and it was not until 1835 that Struve detected the
parallax of α Lyræ. The measurement of this parallax,
together with Bessel's determination of the parallax of
61 Cygni, and Henderson's that of α Centauri, at about
the same time, gave us our first accurate knowledge of
the distances of the fixed stars.
To the thought I have endeavored to express, I must
add another, before I can draw the lesson which I wish
to teach. Great scientific truths become popularized
very slowly, and, after they have been thoroughly
worked out by the investigators, it is often many years
before they become a part of the current knowledge of
mankind. It was fully a century after Copernicus died,
with his great volume—still wet from the press of Nuremberg—in
his hands, before the Copernican theory
was generally accepted even by the learned; and the intolerant
spirit with which this work was received and
the persecution which Galileo encountered more than
half a century later were due solely to the circumstance
that the new theory tended to subvert the popular faith
in the cosmography of the Church. In modern times,
with the many popular expositors of science, the diffusion
of new truth is more rapid; but even now there
is always a long interval after any great discovery
in abstract science before the new conception is translated
into the language of common life, so that it
can be apprehended by the mass even of educated
men.
I have thus dwelt on what must be familiar facts in
the past history of astronomy, because they illustrate
and will help you to realize the present condition of a
much younger branch of physical science; for, in the
transition period I have described, there exists now a
conception which opens a vision into the microcosmos
beneath us as extensive and as grand as that which
the Copernican theory revealed into the macrocosmos
above us.
The conception to which I refer will be at once suggested
to every scientific scholar by the word molecule.
This word is a Latin diminutive, which means, primarily,
a small mass of matter; and, although heretofore often
applied in mechanics to the indefinitely small particles
of a body between which the attractive or repulsive
forces might be supposed to act, it has only recently
acquired the exact significance with which we now
use it.
In attempting to discover the original usage of the
word molecule, I was surprised to find that it was apparently
first introduced into science by the great French
naturalist, Buffon, who employed the term in a very
peculiar sense. Buffon does not seem to have been troubled
with the problem which so engrosses our modern
naturalists—how the vegetable and animal kingdoms
were developed into their present condition—but he was
greatly exercised by an equally difficult problem, which
seems to have been lost sight of in the present controversy,
and which is just as obscure to-day as it was in
Buffon's time, at the close of the last century, and that
is, Why species are so persistent in Nature; why the
acorn always grows into the oak, and why every creature
always produces of its kind. And, if you will reflect
upon it, I am sure you will conclude that this last is by
far the more fundamental problem of the two, and one
which necessarily includes the first. That, of two eggs,
in which no anatomist can discover any structural difference,
the one should, in a few short years, develop an intelligence
like Newton's, while the other soon ends in a
Guinea-pig, is certainly a greater mystery than that, in
the course of unnumbered ages, monkeys, by insensible
gradations, should grow into men.
In order to explain the remarkable constancy of species,
Buffon advanced a theory which, when freed from
a good deal that was fanciful, may be expressed thus:
The attributes of every species, whether of plants or of
animals, reside in their ultimate particles, or, to use a
more philosophical but less familiar word, inhere in these
particles, which Buffon names organic molecules. According
to Buffon, the oak owes all the peculiarities of
its organization to the special oak molecules of which it
consists; and so all the differences in the vegetable or
animal kingdom, from the lowest to the highest species,
depend on fundamental peculiarities with which their
respective molecules were primarily endowed. There
must, of course, be as many kinds of molecules as there
are different species of living beings; but, while the
molecules of the same species were supposed to be exactly
alike, and to have a strong affinity or attraction for
each other, those of different species were assumed to be
inherently distinct and to have no such affinities. Buffon
further assumed that these molecules of organic nature
were diffused more or less widely through the atmosphere
and through the soil, and that the acorn grew to
the oak simply because, consisting itself of oak molecules,
it could draw only oak molecules from the surrounding
media.
With our present knowledge of the chemical constitution
of organic beings, we can find a great deal that is
both fantastic and absurd in this theory of Buffon; but
it must be remembered that the science of chemistry is
almost wholly a growth of the present century, while
Buffon died in 1788; and, if we look at the theory solely
from the standpoint of his knowledge, we shall find in it
much that was worthy of this great man. Indeed, in our
time, the essential features of the theory of Buffon have
been transferred from natural history to chemistry almost
unchanged.
According to our modern chemistry, the qualities of
every substance reside or inhere in its molecules. Take
this lump of sugar. It has certain qualities with which
every one is familiar. Are those qualities attributes of
the lump or of its parts? Certainly of its parts; for,
if we break up the lump, the smallest particles will still
taste sweet and show all the characteristics of sugar.
Could we, then, carry on this subdivision indefinitely,
provided only we had senses or tests delicate enough to
recognize the qualities of sugar in the resulting particles?
To this question, modern chemistry answers decidedly,
No! You would before long reach the smallest mass
that can have the qualities of sugar. You would have
no difficulty in breaking up these masses, but you would
then obtain, not smaller particles of sugar, but particles
of those utterly different substances which we call carbon,
oxygen, and hydrogen—in a word, particles of the
elementary substances of which sugar consists. These
ultimate particles of sugar we call the molecules of sugar,
and thus we come to the present chemical definition of a
molecule, "The smallest particles of a substance in which
its qualities inhere," which, as you see, is a reproduction
of Buffon's idea, although applied to matter and not to
organism.
A lump of sugar, then, has its peculiar qualities because
it is an aggregate of molecules which have those
qualities, and a lump of salt differs from a lump of sugar
simply because the molecules of salt differ from those of
sugar, and so with every other substance. There are as
many kinds of molecules in Nature as there are different
substances, but all the molecules of the same substance
are absolutely alike in every respect.
Thus far, as you see, we are merely reviving in a different
association the old ideas of Buffon. But just at
this point comes in a new conception, which gives far
greater grandeur to our modern theory: for we conceive
that those smallest particles in which the qualities of a
substance inhere are definite bodies or systems of bodies
moving in space, and that a lump of sugar is a universe
of moving worlds.
If on a clear night you direct a telescope to one of
the many star-clusters of our northern heavens, you will
have presented to the eye as good a diagram as we can at
present draw of what we suppose would, under certain
circumstances, be seen in a lump of sugar if we could
look into the molecular universe with the same facility
with which the telescope penetrates the depths of space.
Do you tell me that the absurdities of Buffon were wisdom
when compared with such wild speculations as these?
The criticism is simply what I expected, and I must remind
you that, as I intimated at the outset, this conception
of modern science is in the transition period of
which I then spoke, and, although very familiar to scientific
scholars, has not yet been grasped by the popular
mind. I can further only add that, wild as it may
appear, the idea is the growth of legitimate scientific
investigation, and express my conviction that it will soon
become as much a part of the popular belief as those
grand conceptions of astronomy to which I have referred.
Do you rejoin that we can see the suns in a stellar cluster,
but can not even begin to see the molecules? I must
again remind you that, in fact, you only see points of
light in the field of the telescope, and that your knowledge
that these points are immensely distant suns is an
inference of astronomical science; and, further, that our
knowledge—if I may so call our confident belief—that
the lump of sugar is an aggregate of moving molecules
is an equally legitimate inference of molecular mechanics,
a science which, although so much newer, is as positive
a field of study as astronomy. Moreover, sight is
not the only avenue to knowledge; and, although our
material limitations forbid us to expect that the microscope
will ever be able to penetrate the molecular universe,
yet we feel assured that we have been able by
strictly experimental methods to weigh molecular masses
and measure molecular magnitudes with as much accuracy
as those of the fixed stars.
Of all forms of matter the gas has the simplest molecular
structure, and, as might be anticipated, our knowledge
of molecular magnitudes is as yet chiefly confined
to materials of this class. I have given below some of
the results which have been obtained in regard to the
molecular magnitudes of hydrogen gas, one of the best
studied of this class of substances; and, although the vast
numbers are as inconceivable as are those of astronomy,
they can not fail to impress you with the reality of the
magnitudes they represent. I take hydrogen gas for my
illustration rather than air, because our atmosphere is a
mixture of two gases, oxygen and nitrogen, and therefore
its condition is less simple than that of a perfectly
homogeneous material like hydrogen. The molecular
dimensions of other substances, although varying very
greatly in their relative values, are of the same order
of magnitude as these.[A]
Dimension of Hydrogen Molecules calculated for Temperature of
Melting Ice, and for the Mean Height of the Barometer of the
Sea Level:
Mean velocity, 6,099 feet a second.
Mean path, 31 ten-millionths of an inch.
Collisions, 17,750 millions each second.
Diameter, 438,000, side by side, measure 1⁄100 of an inch.
Mass, 14 (millions3) weigh 1⁄1000 of a grain.
Gas-volume, 311 (millions3) fill one cubic inch.
To explain how the values here presented were
obtained would be out of place in a popular lecture,[B]
but a few words in regard to two or three of
the data are required to elucidate the subject of this
lecture.
First, then, in regard to the mass or weight of the
molecules. So far as their relative values are concerned,
chemistry gives us the means of determining the molecular
weights with very great accuracy; but when we
attempt to estimate their weights in fractions of a grain—the
smallest of our common standards—we can not
expect precision, simply because the magnitudes compared
are of such a different order; and the same is true
of most of the other absolute dimensions, such as the
diameter and volume of the molecules. We only regard
the values given in our table as a very rough estimate,
but still we have good grounds for believing that they
are sufficiently accurate to give us a true idea of the order
of the quantities with which we are dealing; and it will
be seen that, although the numbers required to express
the relations to our ordinary standards are so large, these
molecular magnitudes are no more removed from us on
the one side than are those of astronomy on the other.
Passing next to the velocity of the molecular motion,
we find in that a quantity which, although large, is commensurate
with the velocity of sound, the velocity of a
rifle-ball, and the velocities of many other motions with
which we are familiar. We are, therefore, not comparing,
as before, quantities of an utterly different order,
and we have confidence that we have been able to determine
the value within very narrow limits of error. But
how surprising the result is! Those molecules of hydrogen
are constantly moving to and fro with this great
velocity, and not only are the molecules of all aëriform
substances moving at similar, although differing
rates, but the same is equally true of the molecules
of every substance, whatever may be its state of aggregation.
The gas is the simplest molecular condition of matter,
because in this state the molecules are so far separated
from each other that their motions are not influenced by
mutual attractions. Hence, in accordance with the well-known
laws of motion, gas molecules must always move
in straight lines and with a constant velocity until they
collide with each other or strike against the walls of the
containing vessel, when, in consequence of their elasticity,
they at once rebound and start on a new path with a new
velocity. In these collisions, however, there is no loss of
motion, for, as the molecules have the same weight and
are perfectly elastic, they simply change velocities, and
whatever one may lose the other must gain.
But, if the velocity changes in this way, you may ask,
What meaning has the definite value given in our table?
The answer is, that this is the mean value of the velocity
of all the molecules in a mass of hydrogen gas under the
assumed conditions; and, by the principle just stated,
the mean value can not be changed by the collisions of
the molecules among themselves, however great may be
the change in the motion of the individuals.
In both liquids and solids the molecular motions are
undoubtedly as active as in a gas, but they must be greatly
influenced by the mutual attractions which hold the particles
together, and hence the conditions are far more
complicated, and present a problem which we have been
able to solve only very imperfectly, and with which,
fortunately, we have not at present to deal.
Limiting, then, our study to the molecular condition
of a gas, picture to yourselves what must be the condition
of our atmosphere, with its molecules flying about in all
directions. Conceive what a molecular storm must be
raging about us, and how it must beat against our bodies
and against every exposed surface. The molecules of
our atmosphere move, on an average, nearly four (3·8)
times slower than those of hydrogen under the same conditions;
but then they weigh, on an average, fourteen
and a half times more than hydrogen molecules, and
therefore strike with as great energy. And do not think
that the effect of these blows is insignificant because the
molecular projectiles are so small; they make up by
their number for what they want in size.
Consider, for example, a cubic yard of air, which, if
measured at the freezing-point, weighs considerably over
two pounds. That cubic yard of material contains over
two pounds of molecules, which are moving with an
average velocity of 1,605 feet a second, and this motion
is equivalent, in every respect, to that of a cannon-ball of
equal weight rushing along its path at the same tremendous
rate. Of course, this is true of every cubic
yard of air at the same temperature; and, if the motion
of the molecules of the atmosphere around us could by
any means be turned into one and the same direction,
the result would be a hurricane sweeping over the earth
with this velocity—that is, at the rate of 1,094 miles an
hour—whose destructive violence not even the Pyramids
could withstand.
Living as we do in the midst of a molecular tornado
capable of such effects, our safety lies wholly in
the circumstance that the storm beats equally in all
directions at the same time, and the force is thus so
exactly balanced that we are wholly unconscious of the
tumult. Not even the aspen-leaf is stirred, nor the
most delicate membrane broken; but let us remove
the air from one of the surfaces of such a membrane,
and then the power of the molecular storm becomes
evident, as in the familiar experiments with an
air-pump.
As has already been intimated, the values of the velocities
both of hydrogen and of air molecules given above
were measured at a definite temperature, 32° of our
Fahrenheit thermometer, the freezing point of water;
and this introduces a very important point bearing on our
subject, namely, that the molecular velocities vary very
greatly with the temperature. Indeed, according to our
theory, this very molecular motion constitutes that state
or condition of matter which we call temperature. A
hot body is one whose molecules are moving comparatively
rapidly, and a cold body one in which they are
moving comparatively slowly. Without, however, entering
into further details, which would involve the whole
mechanical theory of heat, let me call your attention to a
single consequence of the principle I have stated.
When we heat hydrogen, air, or any mass of gas, we
simply increase the velocity of its moving molecules.
When we cool the gas, we simply lessen the velocity of
the same molecules. Take a current of air which enters
a room through a furnace. In passing it comes in contact
with heated iron, and, as we say, is heated. But, as
we view the process, the molecules of the air, while in
contact with the hot iron, collide with the very rapidly
oscillating metallic molecules, and fly back as a billiard-ball
would under similar circumstances, with a greatly
increased velocity, and it is this more rapid motion which
alone constitutes the higher temperature.
Consider, next, what must be the effect on the surface.
A moment's reflection will show that the normal
pressure exerted by the molecular storm, always raging
in the atmosphere, is due not only to the impact of the
molecules, but also to the reaction caused by their rebound.
When the molecules rebound, they are, as it
were, driven away from the surface in virtue of the inherent
elasticity both of the surface and of the molecules.
Now, what takes place when one mass of matter
is driven away from another—when a cannon-ball is
driven out of a gun, for example? Why, the gun kicks!
And so every surface from which molecules rebound
must kick; and, if the velocity is not changed by the
collision, one half of the pressure caused by the molecular
bombardment is due to the recoil. From a heated
surface, as we have said, the molecules rebound with an
increased velocity, and hence the recoil must be proportionally
increased, determining a greater pressure against
the surface.
According to this theory, then, we should expect that
the air would press unequally against surfaces at different
temperatures, and that, other things being equal, the
pressure exerted would be greater the higher the temperature
of the surface. Such a result, of course, is
wholly contrary to common experience, which tells us
that a uniform mass of air presses equally in all directions
and against all surfaces of the same area, whatever
may be their condition. It would seem, then, at first
sight, as if we had here met with a conspicuous case in
which our theory fails. But further study will convince
us that the result is just what we should expect in a
dense atmosphere like that in which we dwell; and, in
order that this may become evident, let me next call
your attention to another class of molecular magnitudes.
It must seem strange indeed that we should be able
to measure molecular velocities; but the next point I
have to bring to your notice is stranger yet, for we are
confident that we have been able to determine with approximate
accuracy for each kind of gas molecule the
average number of times one of these little bodies runs
against its neighbors in a second, assuming, of course,
that the conditions of the gas are given. Knowing, now,
the molecular velocity and the number of collisions a
second, we can readily calculate the mean path of the
molecule—that is, the average distance it moves, under
the same conditions, between two successive collisions.
Of course, for any one molecule, this path must be constantly
varying; since, while at one time the molecule
may find a clear coast and make a long run, the very
next time it may hardly start before its course is arrested.
Still, taking a mass of gas under constant conditions, the
doctrine of averages shows that the mean path must
have a definite value, and an illustration will give an
idea of the manner in which we have been able to estimate
it.
The nauseous, smelling gas we call sulphide of hydrogen
has a density only a little greater than that of air,
and its molecules must therefore move with very nearly
as great velocity as the average air molecule—that is to
say, about fourteen hundred and eighty feet a second;
and we might therefore expect that, on opening a jar of
the gas, its molecules would spread instantly through the
surrounding atmosphere. But, so far from this, if the
air is quiet, so that the gas is not transported by currents,
a very considerable time will elapse before the characteristic
odor is perceived on the opposite side of an ordinary
room. The reason is obvious: the molecules must elbow
their way through the crowd of air molecules which already
occupy the space, and can therefore advance only
slowly; and it is obvious that, the oftener they come into
collision with their neighbors, the slower their progress
must be. Knowing, then, the mean velocity of the
molecular motion, and being able to measure by appropriate
means the rate of diffusion, as it is called, we have
the data from which we can calculate both the number
of collisions in a second and also the mean path between
two successive collisions. The results, as we must expect,
are of the same order as the other molecular magnitudes.
But, inconceivably short as the free[C] path of a molecule
certainly is, it is still, in the case of hydrogen gas, 136
times the diameter of the moving body, which would
certainly be regarded among men as quite ample elbow-room.
Although, in this lecture, I have as yet had no occasion
to mention the radiometer, I have by no means forgotten
my main subject, and everything which has been
said has had a direct bearing on the theory of this remarkable
instrument; and still, before you can understand
the great interest with which it is regarded, we
must follow out another line of thought, converging on
the same point.
One of the most remarkable results of modern science
is the discovery that all energy at work on the surface of
this planet comes from the sun. Most of you probably
saw, at our Centennial Exhibition, that great artificial
cascade in Machinery Hall, and were impressed with the
power of the steam-pump which could keep flowing such
a mass of water. But, also, when you stood before the
falls at Niagara, did you realize the fact that the enormous
floods of water which you saw surging over those
cliffs were in like manner supplied by an all-powerful
pump, and that pump the sun? And not only is this
true, but it is equally true that every drop of water that
falls, every wave that beats, every wind that blows, every
creature that moves on the surface of the earth, one and
all, are animated by that mysterious effluence we call
the sunbeam. I say mysterious effluence; for how that
power is transmitted over those 92,000,000 miles between
the earth and the sun is still one of the greatest mysteries
of Nature.
In the science of optics, as is well known, the phenomena
of light are explained by the assumption that
the energy is transmitted in waves through a medium
which fills all space called the luminiferous ether, and
there is no question that this theory of Nature, known
in science as the Undulatory Theory of Light, is, as a
working hypothesis, one of the most comprehensive and
searching which the human mind has ever framed. It
has both correlated known facts and pointed the way to
remarkable discoveries. But, the moment we attempt to
apply it to the problem before us, it demands conditions
which tax even a philosopher's credulity.
As sad experience on the ocean only too frequently
teaches, energy can be transmitted by waves as well as
in any other way. But every mechanic will tell you
that the transmission of energy, whatever be the means
employed, implies certain well-known conditions. Assume
that the energy is to be used to turn the spindles of
a cotton mill. The engineer can tell you just how many
horse-power he must supply for every working-day, and
it is equally true that a definite amount of energy must
come from the sun to do each day's work on the surface
of the globe. Further, the engineer will also tell you
that, in order to transmit the power from his turbine or
his steam-engine, he must have shafts and pulleys and
belts of adequate strength, and he knows in every case
what is the lowest limit of safety. In like manner, the
medium through which the energy which runs the world
is transmitted must be strong enough to do the immense
work put upon it; and, if the energy is transmitted by
waves, this implies that the medium must have an enormously
great elasticity, an elasticity vastly greater than
that of the best-tempered steel.
But turn now to the astronomers, and learn what they
have to tell us in regard to the assumed luminiferous
ether through which all this energy is supposed to be
transmitted. Our planet is rushing in its orbit around
the sun at an average rate of over 1,000 miles a minute,
and makes its annual journey of some 550,000,000 miles
in 365 days, 6 hours, 9 seconds, and 6⁄10 of a second. Mark
the tenths; for astronomical observations are so accurate
that, if the length of the year varied permanently by
the tenth of a second, we should know it; and you can
readily understand that, if there were a medium in space
which offered as much resistance to the motion of the
earth as would gossamer threads to a race-horse, the
planet could never come up to time, year after year, to
the tenth of a second.
How, then, can we save our theory by which we set
so much, and rightly, because it has helped us so effectively
in studying Nature? If we may be allowed such
an extravagant solecism, let us suppose that the engineer
of our previous illustration was the hero of a fairy tale.
He has built a mill, set a steam-engine in the basement,
arranged his spindles above, and is connecting the pulleys
by the usual belts, when some stern necessity requires
him to transmit all the energy with cobwebs. Of course,
a good fairy comes to his aid, and what does she do?
Simply makes the cobwebs indefinitely strong. So
the physicists, not to be outdone by any fairies, make
their ether indefinitely elastic, and their theory lands
them just here, with a medium filling all space, thousands
of times more elastic than steel, and thousands on
thousands of times less dense than hydrogen gas. There
must be a fallacy somewhere, and I strongly suspect it
is to be found in our ordinary materialistic notions of
causation, which involve the old metaphysical dogma,
"nulla actio in distans," and which in our day have
culminated in the famous apothegm of the German
materialist, "Kein Phosphor kein Gedanke."
But it is not my purpose to discuss the doctrines of
causation, and I have dwelt on the difficulty, which this
subject presents in connection with the undulatory theory,
solely because I wished you to appreciate the great
interest with which scientific men have looked for some
direct manifestation of the mechanical action of light. It
is true that the ether waves must have dimensions similar
to those of the molecules discussed above, and we must
expect, therefore, that they would act primarily on the
molecules and not on masses of matter. But still the
well-known principles of wave motion have led competent
physicists to maintain that a more or less considerable
pressure ought to be exerted by the ether waves on
the surfaces against which they beat, as a partial resultant
of the molecular tremors first imparted. Already, in the
last century, attempts were made to discover some evidence
of such action, and in various experiments the
sun's direct rays were concentrated on films, delicately
suspended and carefully protected from all other extraneous
influences, but without any apparent effect; and thus
the question remained until about three years ago, when
the scientific world were startled by the announcement
of Mr. Crookes, of London, that, on suspending a small
piece of blackened alder pith in the very perfect vacuum
which can now be obtained with the mercury pump, invented
by Sprengel, he had seen this light body actually
repelled by the sun's rays; and they were still more startled,
when, after a few further experiments, he presented
us with the instrument he called a radiometer, in which
the sun's rays do the no inconsiderable work of turning
a small wheel. Let us examine for a moment the construction
of this remarkable instrument.
The moving part of the radiometer is a small horizontal
wheel, to the ends of whose arms are fastened
vertical vanes, usually of mica, and blackened on one
side. A glass cap forms the hub, and by the glass-blower's
art the wheel is inclosed in a glass bulb, so that
the cap rests on the point of a cambric needle; and the
wheel is so delicately balanced on this pivot that it turns
with the greatest freedom. From the interior of the
bulb the air is now exhausted by means of the Sprengel
pump, until less than 1⁄1000 of the original quantity is
left, and the only opening is then hermetically sealed.
If, now, the sun's light or even the light from a candle
shines on the vanes, the blackened surfaces—which are
coated with lampblack—are repelled, and, these being
symmetrically placed around the wheel, the several forces
conspire to produce the rapid motion which results. The
effect has all the appearance of a direct mechanical action
exerted by the light, and for some time was so regarded
by Mr. Crookes and other eminent physicists, although
in his published papers it should be added that Mr.
Crookes carefully abstained from speculating on the
subject—aiming, as he has since said, to keep himself
unbiased by any theory, while he accumulated the facts
upon which a satisfactory explanation might be based.
Singularly, however, the first aspects of the new phenomena
proved to be wholly deceptive, and the motion,
so far from being an effect of the direct mechanical
action of the waves of light, is now believed to be a new
and very striking manifestation of molecular motion. To
this opinion Mr. Crookes himself has come, and, in a recent
article, he writes: "Twelve months' research, however,
has thrown much light on these actions, and the
explanation afforded by the dynamical theory of gases
makes what was a year ago obscure and contradictory
now reasonable and intelligible."
As is frequently the case in Nature, the chief effect
is here obscured by various subordinate phenomena, and
it is not surprising that a great difference of opinion
should have arisen in regard to the cause of the motion.
This would not be an appropriate place to describe the
numerous investigations occasioned by the controversy,
many of which show in a most striking manner how easily
experimental evidence may be honestly misinterpreted
in support of a preconceived opinion. I will, however,
venture to trespass further on your patience, so far as to
describe the few experiments by which, very early in
the controversy, I satisfied my own mind on the subject.
When, two years ago, I had for the first time an opportunity
of experimenting with a radiometer, the opinion
was still prevalent that the motion of the wheel was a
direct mechanical effect of the waves of light, and, therefore,
that the impulses came from the outside of the instrument,
the waves passing freely through the glass
envelope. At the outset, this opinion did not seem to
me to be reasonable, or in harmony with well-known
facts; for, knowing how great must be the molecular
disturbance caused by the sun's rays, as shown by their
heating power, I could not believe that a residual action,
such as has been referred to, would first appear in these
delicate phenomena observed by Mr. Crookes, and should
only be manifested in the vacuum of a mercury pump.
On examining the instrument, my attention was at
once arrested by the lampblack coating on the alternate
surfaces of the vanes; and, from the remarkable power
of lampblack to absorb radiant heat, it was evident at
once that, whatever other effects the rays from the sun
or from a flame might cause, they must necessarily determine
a constant difference of temperature between the
two surfaces of the vanes, and the thought at once occurred
that, after all, the motion might be a direct result
of this difference of temperature—in other words, that
the radiometer might be a small heat engine, whose motions,
like those of every other heat engine, depend on
the difference of temperature between its parts.
But, if this were true, the effect ought to be proportional
solely to the heating power of the rays, and a very
easy means of roughly testing this question was at hand.
It is well known that an aqueous solution of alum, although
transmitting light as freely as the purest water,
powerfully absorbs those rays, of any source, which have
the chief heating power. Accordingly, I interposed what
we call an alum cell in the path of the rays shining
on the radiometer, when, although the light on the vanes
was as bright as before, the motion was almost completely
arrested.
This experiment, however, was not conclusive, as it
might still be said that the heat-giving rays acted mechanically,
and it must be admitted that the chief part
of the energy in the rays, even from the most brilliant
luminous sources, always takes the form of heat. But,
if the action is mechanical, the reaction must be against
the medium through which the rays are transmitted,
while, if the radiometer is simply a heat engine, the action
and reaction must be, ultimately at least, between the
heater and the cooler, which in this case are respectively
the blackened surfaces of the vanes and the glass walls of
the inclosing bulb; and here, again, a very easy method
of testing the actual condition at once suggested itself.
If the motion of the radiometer wheel is an effect of
mechanical impulses transmitted in the direction of the
beam of light, it was certainly to be expected that the
beam would act on the lustrous as well as on the blackened
mica surfaces, however large might be the difference
in the resultants producing mechanical motion, in
consequence of the great absorbing power of the lampblack.
Moreover, since the instrument is so constructed
that, of two vanes on opposite sides of the wheel, one
always presents a blackened and the other a lustrous surface
to an incident beam, we should further expect to
find in the motion of the wheel a differential phenomenon,
due to the unequal action of the light on these surfaces.
On the other hand, if the radiometer is a heat
engine, and the reaction takes place between the heated
blackened surfaces of the vanes and the colder glass, it is
evident that the total effect will be simply the sum of
the effects at the several surfaces.
In order to investigate the question thus presented, I
placed the radiometer before a common kerosene lamp,
and observed, with a stop-watch, the number of seconds
that elapsed during ten revolutions of the little wheel.
Finding that this number was absolutely constant, I next
screened one half of the bulb, so that only the blackened
faces were exposed to the light as the wheel turned them
into the beam. Again, I several times observed the
number of seconds during ten turns, which, although
equally constant, was greater than before. Lastly, I
screened the blackened surfaces so that, as the wheel
turned, only the lustrous surfaces of mica were exposed
to the light, when, to my surprise, the wheel continued
to turn in the same direction as before, although much
more slowly. It appeared as if the lustrous surfaces
were attracted by the light. Again I observed the time
of ten revolutions, and here I have collected my results,
reducing them, in the last column, so as to show the corresponding
number of revolutions in the same time:
| CONDITIONS. | Time of ten revolutions. | No. of revolutions in same time. |
| Both faces exposed | 8 seconds. | 319 |
| Blackened faces only | 11 " | 232 |
| Mica faces only | 29 " | 88 |
It will be noticed that 88 + 232 equals very nearly
319. Evidently the effect, so far from being differential,
is concurrent. Hence, the action which causes the
motion must take place between the parts of the instrument,
and can not be a direct effect of impulses imparted
by ether waves; or else we are driven to the most improbable
alternative, that lampblack and mica should
have such a remarkable selective power that the impulses
imparted by the light should exert a repulsive force at
one surface and an attractive force at the other. Were
there, however, such an improbable effect, it must be
independent of the thickness of the mica vanes; while,
on the other hand, if, as seemed to us now most probable,
the whole effect depended on the difference of temperature
between the lampblack and the mica, and if the
light produced an effect on the mica surface only because,
the mica plate being diathermous to a very considerable
extent, the lampblack became heated through
the plate more than the plate itself, then it would follow
that, if we used a thicker mica plate, which would absorb
more of the heat, we ought to obtain a marked difference
of effect. Accordingly, we repeated the experiment
with an equally sensitive radiometer, which we made for
the purpose, with comparatively thick vanes, and with
this the effect of a beam of light on the mica surface was
absolutely null, the wheel revolving in the same time,
whether these faces were protected or not.
But one thing was now wanting to make the demonstration
complete. A heat engine is reversible, and if
the motion of the radiometer depended on the circumstance
that the temperature of the blackened faces of the
vanes was higher than that of the glass, then by reversing
the conditions we ought to reverse the motion. Accordingly,
I carefully heated the glass bulb over a lamp,
until it was as hot as the hand would bear, and then
placed the instrument in a cold room, trusting to the
great radiating power of lampblack to maintain the temperature
of the blackened surfaces of the vanes below
that of the glass. Immediately the wheel began to turn
in the opposite direction, and continued to turn until the
temperature of the glass came into equilibrium with the
surrounding objects.
These early experiments have since been confirmed
to the fullest extent, and no physicist at the present day
can reasonably doubt that the radiometer is a very beautiful
example of a heat engine, and it is the first that has
been made to work continuously by the heat of the sunbeam.
But it is one thing to show that the instrument
is a heat engine, and quite another thing to explain in
detail the manner in which it acts. In regard to the last
point, there is still room for much difference of opinion,
although physicists are generally agreed in referring the
action to the residual gas that is left in the bulb. As
for myself, I became strongly persuaded—after experimenting
with more than one hundred of these instruments,
made under my own eye, with every variation of
condition I could suggest—that the effect was due to the
same cause which determines gas pressure, and, according
to the dynamical theory of gases, this amounts to saying
that the effect is due to molecular motion. I have not
time, however, to describe either my own experiments on
which this opinion was first based, or the far more thorough
investigations since made by others, which have
served to strengthen the first impression.[D] But, after
our previous discussions, a few words will suffice to show
how the molecular theory explains the new phenomena.
Although the air in the bulb has been so nearly exhausted
that less than the one-thousandth part remains,
yet it must be borne in mind that the number of molecules
left behind is by no means inconsiderable. As will
be seen by referring to our table, there must still be no
less than 311,000 million million in every cubic inch.
Moreover, the absolute pressure which this residual gas
exerts is a very appreciable quantity. It is simply the
one-thousandth of the normal pressure of the atmosphere,
that is, of 147⁄10 pounds on a square inch, which is equivalent
to a little over one hundred grains on the same
area. Now, the area of the blackened surfaces of the
vanes of an ordinary radiometer measures just about a
square inch, and the wheel is mounted so delicately that
a constant pressure of one-tenth of a grain would be sufficient
to produce rapid motion. So that a difference of
pressure on the opposite faces of the vanes, equal to one
one-thousandth of the whole amount, is all that we need
account for; and, as can easily be calculated, a difference
of temperature of less than half a degree Fahrenheit
would cause all this difference in the pressure of the
rarefied air.
But you may ask, How can such a difference of pressure
exist on different surfaces exposed to one and the
same medium? and your question is a perfectly legitimate
one; for it is just here that the new phenomena
seem to belie all our previous experience. If, however,
you followed me in my very partial exposition of the mechanical
theory of gases, you will easily see that on this
theory it is a more difficult question to explain why such
a difference of pressure does not manifest itself in every
gas medium and under all conditions between any two
surfaces having different temperatures.
We saw that gas pressure is a double effect, caused
both by the impact of molecules and by the recoil of the
surface attending their rebound. We also saw that when
molecules strike a heated surface they rebound with increased
velocity, and hence produce an increased pressure
against the surface, the greater the higher the temperature.
According to this theory, then, we should expect
to find the same atmosphere pressing unequally on equal
surfaces if at different temperatures; and the difference
in the pressure on the lampblack and mica surfaces of
the vanes, which the motion of the radiometer wheel necessarily
implies, is therefore simply the normal effect of
the mechanical condition of every gas medium. The
real difficulty is, to explain why we must exhaust the air
so perfectly before the effect manifests itself.
The new theory is equal to the emergency. As has
been already pointed out, in the ordinary state of the air
the amplitude of the molecular motion is exceedingly
small, not over a few ten-millionths of an inch—a very
small fraction, therefore, of the height of the inequalities
on the lampblack surfaces of the vanes of a radiometer.
Under such circumstances, evidently the molecules would
not leave the heated surface, but simply bound back and
forth between the vanes and the surrounding mass of
dense air, which, being almost absolutely a non-conductor
of heat, must act essentially like an elastic solid wall confining
the vanes on either side. For the time being,
and until replaced by convection currents, the oscillating
molecules are as much a part of the vanes as our atmosphere
is a part of the earth; and on this system, as a
whole, the homogeneous dense air which surrounds it
must press equally from all directions. In proportion,
however, as the air is exhausted, the molecules find more
room and the amplitude of the molecular motion is increased,
and, when a very high degree of exhaustion is
reached, the air particles no longer bound back and forth
on the vanes without change of condition, but they either
bound off entirely like a ball from a cannon, or else, having
transferred a portion of their momentum, return with
diminished velocity, and in either case the force of the
reaction is felt.[E]
Thus it appears that we have been able to show by
very definite experimental evidence that the radiometer
is a heat engine. We have also been able to show that
such a difference of temperature as the radiation must
produce in the air in direct contact with the opposite
faces of the vanes of the radiometer would determine a
difference of tension, which is sufficient to account for
the motion of the wheel. Finally, we have shown, as
fully as is possible in a popular lecture, that, according to
the mechanical theory of gases, such a difference of tension
would have its normal effect only in a highly rarefied
atmosphere, and thus we have brought the new
phenomena into harmony with the general principles of
molecular mechanics previously established.
More than this can not be said of the steam-engine,
although, of course, in the older engine the measurements
on which the theory is based are vastly more accurate
and complete. But the moment we attempt to go
beyond the general principles of heat engines, of which
the steam-engine is such a conspicuous illustration, and
explain how the heat is transformed into motion, we
have to resort to the molecular theory just as in the case
of the radiometer; and the motion of the steam-engine
seems to us less wonderful than that of the radiometer
only because it is more familiar and more completely
harmonized with the rest of our knowledge. Moreover,
the very molecular theory which we call upon to explain
the steam-engine involves consequences which, as we
have seen, have been first realized in the radiometer;
and thus it is that this new instrument, although disappointing
the first expectations of its discoverer, has furnished
a very striking confirmation of this wonderful
theory. Indeed, the confirmation is so remote and yet
so close, so unexpected and yet so strong, that the new
phenomena almost seem to be a direct manifestation of
the molecular motion which our theory assumes; and
when a new discovery thus confirms the accuracy of a
previous generalization, and gives us additional reason to
believe that the glimpses we have gained into the order
of Nature are trustworthy, it excites, with reason, among
scientific scholars the warmest interest.
And when we consider the vast scope of the molecular
theory, the order on order of existences which it
opens to the imagination, how can we fail to be impressed
with the position in which it places man midway
between the molecular cosmos on the one side and the
stellar cosmos on the other—a position in which he is
able, in some measure at least, to study and interpret
both?
Since the time to which we referred at the beginning
of this lecture, when man's dwelling-place was looked
at as the center of a creation which was solely subservient
to his wants, there has been a reaction to the opposite
extreme, and we have heard much of the utter insignificance
of the earth in a universe among whose immensities
all human belongings are but as a drop in the
ocean. When now, however, we learn from Sir William
Thomson that the drop of water in our comparison is
itself a universe, consisting of units so small that, were
the drop magnified to the size of the earth, these units
would not exceed in magnitude a cricket-ball,[F] and
when, on studying chemistry, we still further learn that
these units are not single masses but systems of atoms,
we may leave the illusions of the imagination from the
one side to correct those from the other, and all will
teach us the great lesson that man's place in Nature
is not to be estimated by relations of magnitude, but
by the intelligence which makes the whole creation his
own.
But, if it is man's privilege to follow both the atoms
and the stars in their courses, he finds that, while thus
exercising the highest attributes of his nature, he is ever
in the presence of an immeasurably superior intelligence,
before which he must bow and adore, and thus
come to him both the assurance and the pledge of a kinship
in which his only real glory can be found.