SOME INTERESTING FACTS ABOUT
EXPLOSIVES
An explosive material consists of a combustible
and of an oxidizing agent for
burning the combustible. Hence it
contains within its own substance the necessary
oxygen for its combustion, so that it
will burn without atmospheric air and therefore
in a confined space.
There are two main kinds of explosive materials—high
explosives and gunpowder.
There are also two main kinds of high explosives—dynamites
and military high explosives. Lastly there are two main kinds
of gunpowders—black, smoky gunpowder
and smokeless gunpowder.
Dynamite is used mostly for commercial
blasting purposes, such as blasting rock in
the construction of railways, and so forth.
Military high explosives are mostly employed
for submarine mines, warheads for
torpedoes, and as bursting charges for high
explosive projectiles.
A high explosive is consumed almost instantly
by what is called a detonative wave;
hence it is said to detonate. When gunpowder
explodes, it is not consumed by a detonative
wave, but burns from the surface,
and the more strongly it is confined, that is
to say, the higher the pressure under which
it is burned, the more rapid is its combustion.
Although the action is rapid, it is yet
much slower than is the action of detonation
of high explosives.
The name gunpowder is a misnomer, for
gunpowder is no longer a powder, but is
made in the form of hard and dense grains
or sticks, according to the use for which it
is intended.
A gunpowder is smoky when its products
of combustion are not all gaseous. Only
about forty-four per cent. of the products of
combustion of black gunpowder is gaseous.
The rest is inert solid matter, which makes
the smoke.
The products of combustion of smokeless
powder, however, are practically all gaseous.
Consequently, weight for weight, it is much
more powerful than black powder.
Black gunpowder is a mechanical mixture
of charcoal, sulphur and saltpeter, the charcoal
and sulphur being the combustible elements,
and the saltpeter the oxidizing
element or the element that supplies the
oxygen.
In smokeless powder the oxygen is held in
chemical union with nitrogen and hydrogen,
but the bond between the nitrogen and the
other elements is weak, so that when ignited
the other more active elements are enabled
easily to unite at the expense of the nitrogen.
In the combustion of all explosive materials,
great heat is generated, and the
force of the explosion is dependent upon the
volume of gases and the high temperature
to which they are raised.
The smokeless powder used in the United
States is made by dissolving a special kind
of guncotton or nitrocellulose in ether and
alcohol, just sufficient of the solvent being
used to gelatinate the nitrocellulose, which is
then stuffed through a forming die into rods.
The rods are cut into sections of about three
diameters long. The die, the invention of
the writer, contains seven mandrels arranged
in such wise that when the material
is forced through the die the bar is multi-perforated
with seven holes at equal distances
apart. The grains or rods of smokeless
powder are then dried for use.
When burned in a cannon, all of the surfaces
of the material are practically instantly
ignited by a small flash charge of black rifle
powder used for the purpose of setting fire to
the charge of smokeless powder. The combustion
in the perforations causes them to become
larger and larger until the grain is all
consumed. This form of grain tends better
to maintain the pressure behind the projectile
in its flight through the gun, and enables
the use of larger charges of powder with
lower pressures than could otherwise be employed.
In fact, it would be impossible to
use a smokeless powder made of pure nitrocellulose
in big guns without the multi-perforations.
In certain European countries where the
multi-perforated powder has not been
adopted, nitroglycerin is employed, combined
with the nitrocellulose, which causes
the material to burn through a greater thickness
in a given time. Thus a smokeless
powder may be made without the multi-perforations,
but smokeless powders containing
nitroglycerin erode the guns and destroy
them very quickly, while guns employing
pure nitrocellulose smokeless powders last
much longer.
When one of our big army or navy cannon
is fired, the time which elapses from the
instant of complete ignition of the powder
charge to the instant that the projectile leaves
the muzzle of the gun is about the fiftieth or
the sixtieth of a second, and in that time the
hard and horn-like smokeless powder material
is burned through only about a sixteenth
of an inch; hence the rate of combustion
or rate of explosion of smokeless powder
in a cannon is about four inches per second,
while it has been ascertained by actual
experiments that the rate of combustion or
rate of explosion of dynamite and other high
explosives is about four miles per second,
so that the rate of consumption of smokeless
powder, as compared to that of a high
explosive, is as are four inches to four miles.
As the time required for the projectile to
be thrown from a twelve-inch cannon is only
about the sixtieth of a second, sixty of these
huge guns could be placed side by side and
fired by electricity one after the other, while
grandfather’s clock is making but one tick.
Our ideas of duration are but relative.
We have seen that the combustion in a cannon,
though very rapid to our senses, is actually
very slow indeed as compared with
the much more rapid combustion of a high
explosive; and great as is the speed of the
detonative wave, yet the speed of the earth
in its orbit is four times as great.
If a celestial giant with a huge dynamite
bomb the size of the earth itself were to approach
the earth in its flight through space,
and detonate the bomb immediately behind
the earth, it would take half an hour for the
bomb to explode, that is to say, it would take
half an hour, or thirty minutes, for the explosive
wave to pass through the eight thousand
miles of its diameter. As the speed of
the earth in its orbit is four times as great
as that of the explosive wave, the earth
would rush away, leaving the bomb about
thirty thousand miles behind by the time it
had completely exploded. If the interstellar
ether were a high explosive mixture and
were to be set off by the bomb, the earth
would pass on clear around the sun, and
while coming back, about six months later,
would meet the explosive wave still going.
It would require nearly a year for such a
detonative wave to reach our sun from the
earth.
We have seen that if the earth were a ball
of dynamite, it would require half an hour
to explode. If the sun were a mass of dynamite
it would require about two and a half
days to explode.
We frequently hear the theory advanced
that planets and suns sometimes explode
from pent-up forces within them, and that
our earth might possibly blow up. Now,
the force exerted by a high explosive is dependent
entirely upon the pressure capable
of being exerted by the gases liberated by
the explosion. The pressure exerted by the
most powerful high explosives has been estimated
to be about 500,000 pounds to the
square inch. Consequently, were the whole
molten interior of the earth to be replaced
with dynamite and detonated, the explosion
that would follow would not lift the earth’s
crust. The superincumbent weight of the
earth’s crust is greater than would be the
pressure exerted by the dynamite.
If it were possible to throw a projectile
from the earth to the nearest fixed star,
Alpha Centauri, it would take about four
years for the light of the flash to reach that
star. The sound, if it could travel through
ether, would reach there about four million
years later. The projectile, traveling more
than twice as fast as sound, would reach
there in about two million years.
When one of our big twelve-inch cannon is
fired, the projectile, weighing a thousand
pounds, has a muzzle energy, stated in mechanical
terms, of about 50,000 foot tons,
that is to say, its energy is equal to 50,000
tons falling from a height of one foot—energy
enough to lift two 25,000-ton battleships
to the height of a foot.
As the projectile weighs half a ton, the
energy is equal to that which would be developed
by dropping the projectile from a
height of more than twenty miles, making
no account of the resistance of the atmosphere.
Dropping upon a piece of armorplate too
hard and thick for the projectile to penetrate,
the heat developed would be sufficient
to melt 750 pounds of cast iron.
When one of these projectiles is fired from
the gun directly against twelve-inch armorplate,
which the projectile is capable of penetrating,
the hard-tempered steel plate in
front of the projectile is fuzed or rendered
plastic from the heat generated by the
energy of the impact, and is forced like wax
from the path of the projectile.
There are many popular errors regarding
the action of explosive materials. One of
the most notable is the opinion that the action
of dynamite is downward, and that if a
body of high explosive be detonated on the
surface of the earth the main effect is downward.
The exact opposite is the truth. When a
mass of explosive is detonated, it is converted
practically instantly into a ball of incandescent
gases and vapors under very
high pressure. When confined the gases act
to disrupt their container.
When a large steel projectile is charged
with a high explosive, like picric acid, and
the explosive detonated, the walls of the projectile
are not only broken but they are also
torn, twisted and shredded, and so quick is
the action that the inner surface of the
metal is compressed and densified against
the outer metal.
For this reason it is easy to tell from the
character of the fragments of a projectile
whether or not a high explosive or an explosive
of inferior power was employed, that is
to say, whether or not the explosion was of
high order or of low order.
There is one false belief about the action
of high explosives that has been about the
hardest of any to kill, and the cost of killing
it has been very expensive. Furthermore, it
possesses more lives than the proverbial
nine-lived cat. This belief is that five hundred
pounds or so of dynamite exploded
upon a warship or upon coast fortifications
would destroy ship or fortifications, and
that a few of such large bombs of dynamite
dropped in a city would lay the city in
ruins.
Upon the advent of the aeroplane and the
dirigible balloon, it was confidently believed
that the aerial bomb would quickly become
the most destructive implement of warfare.
It was prophesied that should war come between
England and Germany, London would
soon be reduced to a heap of ruins by bombs
dropped from the German Zeppelins.
Several years before the European War
broke out, I predicted that Zeppelin bombs
would not and could not by any possibility
work very wide destruction, and events have
since vindicated my prediction. I pointed
out the fact that should a hundred Zeppelins
visit the city of London, once a day, for a
year, returning to their base without mishap,
and each Zeppelin succeed in destroying
two buildings, the destruction would just
about keep up with the growth of that city,
for they build in London sixty thousand
houses a year.
We all remember the destructive powers
that were predicted for the fifteen-inch
Zalinski pneumatic dynamite guns that were
mounted at Sandy Hook and at San Francisco
at enormous Government expense.
These guns were capable of throwing with
compressed air about six hundred pounds of
nitrogelatin to a distance of from a mile-and-a-half
to two miles. It was popularly
believed that one of these bombs striking
upon a huge armorclad warship would utterly
destroy it.
Also two of these guns were mounted in
a sort of cruiser called the Vesuvius. During
the Spanish War the Vesuvius was taken
down to Cuba, and in one action several of
the huge bombs were thrown upon the earthworks
and fortifications of the Spanish.
They succeeded merely in mussing up the
green, grassy effect. They did no material
damage, for the reason that the action of the
explosive was nearly all upward into the air.
When the pneumatic dynamite gun was
promulgated, it was popularly believed that
all high explosives were exceedingly sensitive,
and that it was necessary to get them
out of the gun very gently if they were to
be thrown from ordnance.
The writer was the first to dispel this
folly, through the invention of Maximite, a
high explosive which will stand not only the
shock of being fired from heavy guns at high
velocities, but which will also, without exploding,
stand the far greater shock of penetrating
the heaviest armorplate—armorplate
as heavy as the projectile will stand
to pass through without breaking up.
While I was working upon Maximite and
trying to get the Government to adopt it,
Congress appropriated the money for building
an eighteen-inch gun for testing a shell
invented by Louis Gathmann, which was
intended to destroy battleships by exploding
the shell on the outside of their heavy armorplate,
it being believed that if five hundred
pounds of guncotton were to be fired against
the side of an armored ship and exploded,
the whole side of the ship would be blown
in and the vessel destroyed.
The gun employed by Gathmann was essentially
the same type of gun as that previously
designed by me, and explained in a
lecture by me before the Royal United Service
Institution of Great Britain in 1897, and
illustrated in a book of mine published the
same year by Eyre & Spottiswoode, British
Government printers, except that the
bore of my gun, which was of the same
weight as that of the Gathmann gun, was
greater. With my gun, however, I proposed
to throw armor-piercing projectiles, or projectiles
capable of penetrating an object
struck and exploding inside of it. I did not
believe that a quantity of high explosive that
could be thrown in a shell and exploded on
the outside of a heavily armored ship would
destroy it, but believed it necessary that the
explosive should penetrate and explode inside
the ship, and within earthworks and
fortifications in order to destroy them.
Maximite was adopted by the United
States Army in 1901. It was during that
same year that the experiments were conducted
with the Gathmann shell at Sandy
Hook. I attended those experiments.
Two Kruppized armorplates, each eleven-and-a-half
inches thick, sixteen feet long,
and seven-and-a-half feet wide, and each
weighing 47,000 pounds, were set up, one
as a target for the Gathmann shell and
the other as a target for the regular
United States twelve-inch Army Rifle. Each
of the plates was backed by supports to represent
the same strength as though mounted
on a battleship.
The Gathmann shell weighed about eighteen
hundred pounds, and carried about five
hundred pounds of guncotton, while the
Government twelve-inch shell weighed a
thousand pounds and carried only twenty-three
pounds of Maximite. The Gathmann
shell had a soft nose, which collapsed on the
plate at the instant before the explosion of
the shell, so that the guncotton might explode
fairly against the side of the plate.
At the first shot of the Gathmann gun,
the projectile struck the plate squarely and
exploded, but the only effect upon the plate
was to leave a great yellow smudge on its
face. The plate was neither cracked nor
pushed back. Several more shots of the
Gathmann gun were fired, and although,
under the heavy pummeling, the plate was
pushed back and broken through, up and
down, it was not otherwise injured.
Then the Government twelve-inch gun was
fired at the other plate. The first shell contained
nineteen pounds of high explosive,
and it passed through the plate, leaving a
clean round hole, and exploded behind the
plate without breaking it. The next shell
contained twenty-three pounds of Maximite,
and the fuze was timed to go off a little
quicker. This shell exploded in the plate
when about two-thirds through, with the result
that a hole was blown in the plate as
big as a barrel, and the plate shattered into
fragments.
One would think that these tests would
suffice forever to seal the doom of the Gathmann
type of shell. Nevertheless, it matters
not what Army and Navy officers may learn
by experience, or know without experience,
Congress does not know and does not understand,
and depends far more upon think-so
than upon experience. The result is that
Government officers are often compelled, as
in the case of the Zalinski dynamite gun and
the Gathmann shell, to waste large sums of
money while they know very well beforehand
exactly what the results will be, and
that the tests will prove the devices to be abject
failures. Even after the failure of the
Gathmann shell, another shell of almost
identical conception and purpose was made
and tested under a Congressional appropriation,
to be relegated to the scrap-heap of
failures.
It is very fortunate that things happen to
be as they are in the cosmos and that the
action of a high explosive when exploding
against a massive body is to rebound from
that body on the line of least resistance. It
is for this reason that more damage is not
done by great explosions.
One of the biggest explosions in the history
of gunpowder manufacture occurred at
Pleasant Prairie, Wisconsin, on the 9th of
March, 1911, when it was estimated that a
thousand tons of black blasting powder blew
up. Glass was broken over a very wide area.
Some glass was broken in Chicago, about
fifty miles distant.
But neither the walls nor the foundations
of buildings were greatly disturbed even but
a few miles from the explosion. In the village
of Pleasant Prairie, at a distance of but
two miles, although the buildings were very
much damaged the inhabitants continued to
occupy them.
Early in the morning of July 30, 1916, a
very large quantity, certainly several hundred
tons, of high explosive materials blew
up in New York Harbor, not far from Ellis
Island. A large quantity of shrapnel ammunition
and other ammunition went up in
the blast, their fragments raining all over
the surrounding water. There was but very
little loss of life, and the actual material
damage to buildings in Jersey City, Manhattan
and Brooklyn was astonishingly
small, except the loss from broken glass.
Why is it, then, that so much glass is
broken and at such long distances, while the
foundations and walls of buildings suffer but
little injury? Let me explain. When a
quantity of high explosive detonates, a wave
of atmospheric compression is sent outward
in all directions by the explosion. It is, in
fact, a huge sound wave, and moves exactly
at the speed of sound—about eleven hundred
feet per second. Of course, buildings or
other structures or objects near enough to
the explosion to be struck by the expanding
gases themselves, or by the atmosphere immediately
propelled forward by them like a
projectile, may be destroyed, but the area
over which this action occurs is so circumscribed
that no great damage is apt to result
at distances beyond a few hundred feet.
However, the great sound wave may travel
to a distance of many miles. Consequently,
as a result of the explosion just referred to,
about a million dollars’ worth of glass was
broken in New York City alone. One would
naturally suppose that the fragments of
window glass broken in this manner would
fall inside a building, but they do not. Almost
always they fall outside into the street.
The reason for this is that the wave of compression,
striking a pane of glass, forces it
inward nigh to the breaking point, and then
as the wave of compression moves on, followed
by a partial vacuum, the glass, springing
outward to fill the void, breaks, and falls
into the street.
An interesting incident of this great explosion
was staged at Ellis Island. There
were a goodly number of immigrants on the
Island at the time, congregated from the four
corners of the earth, some of whom had come
to America to seek their fortunes in this
land of freedom-from-everything-except-freedom,
but many had come to find quiet
and security from war’s alarums. Few of
them, indeed, had ever felt the comfort of
an overcoat, but many had dreamed of some
happy day when they would sport a veritable
fur-lined overcoat.
When the great explosion came it sounded
like the crack of doom, and most of the immigrants
believed it to be the real thing and
proceeded with agitated precipitation to get
their souls ready for rapid transit over the
Great Divide.
All eyes naturally were averted to the
celestial concave, aglare with the great conflagration,
when suddenly, to the confounding
amaze of all, a large flock of fur-lined
overcoats began tumbling down out of the
heavens all over the Island. It is true they
were lined merely with sheep’s fur, but even
such a garment is as much the pride of the
Northern European peasant as is the broad,
glad-colored sombrero the pride of the Mexican
peon.
As the Government statute books and
rules and regulations governing immigrants
contain no provision for the disposal of such
species of manna as heaven-sent overcoats,
the immigrants were the beneficiaries.
Great as are such explosions as that at
Pleasant Prairie and that in New York Harbor,
they are but little things indeed compared
with the explosions that sometimes accompany
volcanic eruptions. Mother Earth
is the greatest of all explosive manufacturers.
Water seeping down into the earth’s crust
and trapped in large quantities in the neighborhood
of volcanoes sometimes becomes
heated to high incandescence—heated until
it is no longer water or steam, but mingled
oxygen and hydrogen, far above the temperature
of their dissociation—under a pressure
so great that they occupy a space no larger
than the original water; consequently the entrapped
waters exert a pressure as great as
the strongest dynamite.
The most notable volcanic explosion that
ever occurred in historic time was when that
old extinct volcano, Krakatoa, in the Straits
of Sunda, that had been sleeping for thousands
of years, was literally blown into the
sky by the pressure of the pent-up gases beneath
it.
This great eruption occurred in 1883.
More than sixty thousand persons were
killed. The captain of a tramp steamer,
who happened to be passing in the vicinity
of Krakatoa at a distance of some miles, a
short time before the explosion occurred,
saw a very strange disturbance in the sea in
the direction of the old mountain. Taking
his glass he saw a perfect Niagara of water
pouring into an enormous fissure that had
opened in the earth. He was struck with consternation
and rightly imagining that something
very serious was likely soon to happen,
he put on all steam to escape, and luckily
he had reached a point which enabled him
to survive the effects of the awful blast when
it came.
The vast mass of water which had tumbled
into the bowels of the earth was immediately
trapped by the closing of the great
fissure down which it had poured. The
water was quickly converted by the intense
heat into a veritable high explosive, with the
result that the massive mountain was literally
blown bodily skyward, and fell in huge
fragments into the surrounding sea. The
shock was so great that it was felt clear
through the earth, and an immense tidal
wave was set going which encircled the
earth. The opposing portions of the great
wave, meeting in the lower Atlantic, flowed
up even to the coast of France. An atmospheric
wave passed around the earth
three times. It is estimated that the amount
of volcanic mud that was discharged from
the mountain during the eruption was more
than the muddy Mississippi discharges into
the Gulf of Mexico in two hundred years.
There was so much impalpably fine volcanic
dust blown into the upper atmosphere
that it did not entirely settle out of
the air for more than two years, which period
was noted for its beautiful glowing sunsets,
due to the illumination of the fine dust suspended
in the upper air.
As the ax is to the woodsman, so are high
explosives to the engineer. With dynamite
he hews down the hills, fills the valleys
and tunnels the mountain-range to make a
straight and even way for the locomotive.
He cuts canals through the width of the land,
uniting rivers and seas.
Always in the van of civilization, there is
heard the churn of the rock-drill and the
echoing crash and roar of the dynamite
blast.
Also it is the huge high explosive shell
that makes way for the march of modern
armies, and high explosive mines and torpedoes
are the terror of the underseas.
All forms of dynamite are high explosives,
and all high explosives may fairly be called
dynamite.
Smokeless gunpowder is actually but a
modified form of high explosive. It is dynamite
that has been chained and tamed by the
chemist’s cunning, so that it will burn without
detonation, and thus permit the utilization
of its awful energy to hurl shot and shell
from war’s great guns.
Thus it is that dynamite in its varied
forms deserves the high place with steam
and electricity as one of the great triumvirs
that have been the architects of the modern
world.