In examining the question, whether Theophrastus, Pliny, and
in general the ancient Greeks and Romans, were acquainted
with our saltpetre, or at what period it became known, I shall
perhaps meet with as little success as those who have preceded
me in the same research1190. I shall therefore be satisfied if
competent judges allow that I have contributed anything new
that can tend to illustrate the subject.
Our saltpetre, which is commonly called nitrum, and sometimes,
though more rarely, sal nitræ, is a neutral salt composed
of a peculiar acid, named the acid of saltpetre or nitric acid,
and that alkali called potash. The characters by which it is
most readily distinguished from other salts are its cooling
taste, its fusibility when exposed to a small degree of heat,
and in particular its so-called deflagration; that is, the property
it has when placed in the fire, or on an ignited body, or
when melted in a crucible, with a combustible substance, of
suddenly bursting into a very bright flame, by which it loses
its acid, and nothing remains but a carbonate of potash. The
principal use of it is in making gunpowder, and for the preparation
of that acid known under the name of aquafortis1191,
which is employed in various ways.
Native saltpetre is so rare, that Cronstedt was not acquainted
with it. At present, however, it is known to occur in
the East Indies, in the lower part of Italy, also in Portugal1192,
Spain, America, and some other countries1193. But almost all
the saltpetre obtained in Europe is produced partly by nature
and partly by art. The putrefaction of organic bodies gives
rise, under certain circumstances, to nitric acid, which in general
combines with calcareous earth wherever it finds it,
and forms the so-called earthy saltpetre. This is decomposed
by potash, and the latter uniting with the acid forms common
saltpetre. Sometimes also it is found that the nitric acid,
instead of being united with calcareous earth, is combined with
soda, which produces the so-called cubic saltpeter1194. Both
these saline substances, but the earthy more frequently than
the cubic, are often found on effloresced walls; and both are
then comprehended under the common names of Mauersalz
or Mauerbeschlag, sal murale.
This efflorescence on walls was observed, in all probability,
at a very early period, especially as it is produced in many
parts in great abundance, and as it makes itself perceptible
by the decay of walls, which it seems to corrode. It is the
plague or leprosy of houses mentioned in the Mosaic code of
laws. As the ancients were so much inclined to expect
medicinal virtue in all natural bodies, there is reason to think
that they soon collected and made trial of this saline incrustation.
That this indeed was actually the case, and that they
gave the name of nitrum to this saline mass, may be proved
from their writings. Their nitrum, however, must have been
exceedingly various in its properties. For this incrustation is
not always calcareous saltpetre; it is often soda1195, mixed with
more or less calcareous earth; and sometimes it consists of
salts of sulphuric acid. In modern times, on closer examination,
other salts of nitric acid have been found in the incrustation
of walls, such as flaming saltpetre or nitrate of ammonia,
bitter saltpetre or nitrate of magnesia; but of these no mention
can be expected in the works of the ancients.
Substances so different ought not indeed to have been all
named nitrum; but before natural history began to be formed
into a regular system, mankind in general fell into an error
directly contrary to that committed at present. Objects essentially
different were comprehended under one name, if
they any how corresponded with each other even in things
accidental. Whereas at present every variety, however small,
obtains a distinct appellation; because many wish to have the
pleasure, if not of forming new species, at any rate of giving
new names. The elephant and rhinoceros were formerly
called oxen; the sable and ermine were named mice, and the
ostrich was distinguished by the appellation of sparrow. In
the like manner, calcareous saltpetre and alkali might be
called nitrum. The ancients, however, gave to their nitrum
some epithets, but they seem to have been used only to denote
uncommon varieties.
Now, as the ancients were not acquainted with any accurate
method of separating and distinguishing salts, it needs excite
no wonder that they should ascribe to their nitrum properties
which could not possibly be united in a salt, and much less
exist in our saltpetre. But as they were neither acquainted
with aquafortis nor manufactured gunpowder, and as no
particular use of calcareous saltpetre was known, the nitrum
most valuable to them must have been that which consisted
chiefly of soda, and which consequently could be employed
in washing, in painting, and in glass-making.
It is well known that in warm countries this alkali effloresces
here and there from the earth, particularly in a dry soil, and
even in such quantity as to be employed in commerce. Hence
it may be readily comprehended why this effloresced salt,
which is very often mixed with common salt, obtained the
name of nitrum.
The important discovery, that a similar salt, having the
like properties, and applicable to the same uses, named at present
soda, may be obtained from the ashes of certain plants,
was first made, in my opinion, by the ancient Egyptians or
Arabians1196. This salt also, at least by the Greeks, was named
nitrum, or considered as a species of it. By the incineration
of the plants this salt was rendered slightly caustic; and it
then became moist in the air, and deliquesced when not preserved
in very close vessels. It was therefore like those salts
which are obtained, in the same manner, from the ashes of
all other plants; though the latter are essentially different
from the former, and in the course of time obtained the peculiar
appellation of potash or pearlash. One can hardly be
surprised that the ancients were not able to distinguish soda
from potash, especially as they were both obtained from vegetable
ashes.
But were the ancients, under the ambiguous name of nitrum,
acquainted with our saltpetre? There is certainly reason
to think that it became known to them by lixiviating
earths impregnated with salts. There are, as already said,
not only in India but also in Africa, and particularly in
Egypt, earths which, without the addition of ashes or potash,
give real saltpetre, like that of the rubbish-hills on the road
from new to old Cairo1197, and like the earth in some parts of
Spain. It is a knowledge only of this natural kind of saltpetre,
which required no artificial composition, that can be
allowed to the ancients, as it does not appear by their writings
that they were sufficiently versed in chemistry to prepare the
artificial kind used at present.
But even admitting that they had our saltpetre, where and
by what means can we be convinced of it? Is it to be expected
that any of the before-mentioned characters or properties
of this salt should occur in their writings? They
neither made aquafortis nor gunpowder; and they seem
scarcely to have had any occasion or opportunity to discover
its deflagration and the carbonization thereby effected, or,
when observed, to examine and describe it. No other use of
our saltpetre which could properly announce this phenomenon
has yet been known. How then can it be ascertained
that under the term nitrum they sometimes meant our saltpetre?
Those inclined to believe too little rather than too much,
who cannot be satisfied with mere conjectures or probabilities,
but always require full proof, will acknowledge with me,
that the first certain accounts of our saltpetre cannot be expected
much before the invention of aquafortis and gunpowder.
It deserves also to be remarked, that the real saltpetre,
as soon as it became known, was named also nitrum; but, by
way of distinction, either sal nitrum, or sal nitri, or sal petræ.
The first appellation, from which our ancestors made salniter,
was occasioned by an unintelligible passage of Pliny, which I
shall afterwards point out. The two other names signify,
like sal tartari, sal succini, a salt which was not nitrum but
obtained from nitrum. Sal-nitri, therefore, or salniter, was
that salt which, according to the representation of the ancients,
was separated by art from nitrum, yet was essentially
different from the nitrum or soda commonly in use. Biringoccio
says expressly, that the artificial nitrum, for the sake
of distinction, was named, not nitrum, but sal nitrum.
The name nitrum is of great antiquity, and seems to have
been conveyed from Egypt and Palestine to Greece, and
thence to Italy and every part of Europe. For it is evidently
the neter mentioned by the prophet Jeremiah, chap.
ii. ver. 22; and which occurs also in the Proverbs of Solomon,
chap. xxv. ver. 20. But whether the name nitrum, as
Jerome says1198, be derived from the Egyptian province Nitria,
whence it was exported in great abundance, or the name of
the province was derived from nitrum, is a question of little
importance in regard to this research. Nitron is mentioned
by Herodotus, where he describes the Egyptian method of
embalming dead bodies1199; by some of the Greeks the word
was written and pronounced litron. In the same manner
people say nympha and lympha. In order to avoid confusion,
I shall here call the nitrum of the ancients nitrum, and
the nitrum of the mineralogists saltpetre.
In the course of time men became acquainted with the
purer, more useful, and cheaper mineral alkali which was
furnished, under the name of soda, by the Moors and inhabitants
of the southern countries, who had learned the method
of preparing it. The vegetable alkali also was always more
and more manufactured in woody districts, as an article in
great request, and sold under the name of potash, cineres clavellati.
All knowledge of the impure alkali from the incrustation
of walls was then lost; and as there was no further
need of guarding against confusion, it was not longer thought
worth while to name saltpetre sal nitri: it was called nitrum;
and the oldest signification of this word being forgotten, it
was admitted without further examination, that the nitrum of
the ancients was nothing else than our saltpetre.
In the sixteenth century some learned Europeans, while
travelling through the East, heard the name natrum given to
the mineral alkali which was then exported as an article of
commerce, and introduced in their works this transformation
of the ancient word nitrum. This appellation was employed
by the systematic mineralogists, who, giving themselves little
trouble about the original meaning of words, and taking care
only to avoid confusion, called the mineral alkali also natrum,
and applied the name of nitrum to saltpetre. As far as I
know at present, it was first stated by Peter Bellon and Prosper
Alpinus1200, that the mineral alkali was in the East called
natrum. The former returned in 1549, and the latter was
still in Cairo in 1580.
This word was adopted in mineralogy by Linnæus, in the
year 1736, as the name of a species, in which he comprehended
for the first time the alkaline incrustation found on
walls. In this he is followed by Wallerius, who includes also
the mineral alkali from the East. Afterwards the word natrum
was employed in the same sense by all mineralogists.
It deserves here to be remarked, that Boyle had even examined
and determined the difference between the fixed and
volatile alkalies; but that mineralogists and chemists, till the
latest periods, believed that all fixed alkali arose, or at least
was obtained, by the incineration of plants. The difference
between the mineral and vegetable alkalies was first defined,
in a proper manner, by the exertion of the German chemists
Pott, Model and Marggraf1201; especially after the last had
proved, in the year 1758, that the basis of common salt was
not, as had before been generally believed, an alkaline earth,
but a fixed alkali, to which, because it was in many of its
properties different from the fixed vegetable alkali, he gave
the name of fixed mineral alkali. Soon after this substance
was discovered in mineral springs; and Model and others
have shown that it is not essentially different from that which
in the East is called natrum.
It is singular, and yet may be accounted for, that since
that time many have spoken of the nitrum and natrum of the
ancients, though they are only different pronunciations of the
same word; and natrum is never found in the works of the
Greeks or the Romans, and not even in writings of the middle
ages.
But if the greater part of what I have here said should be
considered only as conjecture, it must nevertheless be acknowledged
that it is deduced from the nature of the thing;
and when impartially compared with what we read in the
ancients, the latter I hope will be better understood than it
hitherto has been; the impropriety of many readings will become
apparent, and the truth of this conjecture be admitted.
Were I here to relate everything that we read of nitrum,
in order to compare it with nature and to examine it thoroughly,
I should be obliged to extend this article to a greater
length than might be agreeable to the reader. I shall therefore
give only the principal proofs of my assertion, premising,
that doubts which might be excited by single passages not
here mentioned, will, on a closer comparison, vanish without
my assistance. But I maintain that those who wish to explain
the old names of natural objects must relate everything
said of them, and not that alone which is favourable to their
opinion, and which may be often contradicted by what was
purposely or accidentally concealed. The first part of such
an examination is always a careful collection from the writings
of the ancients of all the predicates of the natural object, the
systematic name of which one is endeavouring to prove.
There is reason however to conjecture, that the ancients,
in the history of their impure nitre, the manner of obtaining
which the Romans at least had no opportunity themselves of
seeing, for Pliny says expressly that it was not procured in
Italy, fell into many errors and mistakes, which at present
cannot all be explained.
Hence it happened that the ancients did not understand
the art of purifying the salt which they obtained from minerals;
and therefore they were obliged to use it in the same
impure state in which they found it. On this account they
considered each natural mixture as a peculiar kind; gave to
the greater part of them, or those most useful, particular
names; and of these recommended for different purposes
those which, according to their purity or mixture, or according
to other circumstances, were the most convenient. It is
not probable that all these varieties could be again found out
or defined; and it seems to be of little importance, when it is
known that the names denote nothing more than the varieties
of a mineral.
In this examination it is to be regretted that the book of
Theophrastus, in which he expressly treated of nitrum, has not
been preserved. But it may be believed, even without the
testimony of Pliny, that he was one of the most accurate and
acute naturalists among the ancients, and that he gave the best
account of this substance1202. It must, however, be admitted
that Pliny thoroughly understood this author, and gave a correct
extract from him, and that the transcriber fell into no
mistake.
That the nitrum of the ancients was an alkali more or less
impure, but not saltpetre, has been long admitted by those who
had the least knowledge of mineralogy, as well as by the most
sagacious physicians. The grounds for this opinion, as far as I
have yet learned, are as follows: more indeed might be found,
but these are sufficient to afford a complete proof. Galen, a
cautious writer, says that nitrum was in general burnt, by
which means its effects were strengthened1203. Had it been saltpetre,
it is impossible that the ancients should not in burning
it have observed its deflagration, and this property is too remarkable
not to have been mentioned. But nothing is to be
found that can with any probability be supposed to allude
to it.
But should it be admitted without any grounds that it was
not an alkali but saltpetre which they burnt, it must certainly
have been carbonized; for a burning body may easily have
fallen into the crucible, and in general nitrum seems to have
been burnt in an open fire, like our lime, because Pliny, speaking
of the Egyptian, considers the contrary as somewhat uncommon.
Physicians then, at any rate, must have observed,
that a body very different both in its appearance and effects
was produced from saltpetre by burning, but which could not
be used for any other purpose than that salt. Of this however
we do not find the least intimation.
But nitrum was undoubtedly soda, and on that account
when burnt must have become more caustic as well as stronger
in most of its effects, and in this respect similar to potash,
since [owing to impurities] it in the same manner became
moist and deliquesced in the air. What Pliny relates of the
Egyptian nitrum becomes then intelligible. The latter, he
says, was transported in pitched vessels, because it would
otherwise have deliquesced; and he afterwards adds, that it
was burnt before it was sent off. Had he known that the latter
was the cause and the former the effect, he would have
mentioned the latter first; but his whole extract, in regard to
nitre, is written in general without order. The vessels, no
doubt, were of clay; but whether he means in what he adds
that they were not burnt but only baked in the sun, or that
before they were filled they were completely dried in the sun,
has been determined by no commentator. To me the latter
is the more probable. Pliny also mentions another circumstance
in regard to the burning of the Egyptian nitrum;
namely, that it must be done in a close vessel, otherwise it
would decrepitate or fly off. This is perfectly intelligible,
when it is considered that it contained a great deal of common
salt, which alone possessed the property of decrepitating;
and it is well known in mineralogy that native soda, and even
that which in modern times has been introduced into our collections
from Tripoli, and of which I have in my possession a
specimen, contains common salt1204, and often in cubic crystals.
Pliny had just reason to add, that nitrum otherwise does not
properly decrepitate. The ancients were well acquainted with
the resemblance of their nitrum to lime, and especially of that
which was burnt. On this account, because the Egyptian
was exported after it had been burnt, it could easily be mixed
with quicklime, or, as Pliny says, be adulterated. But the
proof which he gives he does not seem to have thoroughly
understood. The Egyptian must at all times have been caustic
(pungens) even without lime; but that which was mixed
with lime could not so speedily or completely dissolve on the
tongue as that which was pure, and left behind it more earth.
What he says of a test by the smell, I cannot understand in
any other manner than that burnt lime, when moistened with
water, diffused that disagreeable vapour observed in apartments
the walls of which have been newly plastered; though
when the quantity is small this is hardly perceptible.
If I understand Theophrastus1205 properly, he seems to say,
that if nitrum be burnt as soon as it is dug up, it communicates
heat to water in the same manner as lime. It may here
be seen how great a resemblance the ancients found between
their nitrum, alkaline earth and lime.
The similarity of wood-ashes to the nitrum of the ancients,
which they acknowledged, proves also that it was in reality
an alkaline salt. We are told by Theophrastus1206 that nitrum
was said to be produced from oak-ashes; and Pliny1207, who
borrowed from this writer, remarks that it was certain the
ashes of that wood were nitrous. He ascribes also to burnt
wine-lees the nature and properties of nitrum1208. Nay he considers
as a kind of nitrum those saline ashes which, in many
countries destitute of salt, were used for seasoning food, and
which were prepared by pouring sea-water or salt brine over
burning piles of wood, gradually and in small quantities, so
that the fire was not extinguished, by which means the water
evaporated, leaving the salt behind, but mixed indeed with
charcoal, ashes, earth, and alkaline salts; consequently it must
have been moist, or at any rate nauseous, if not refined by a
new solution. This method of preparing or boiling salt, which
perhaps is the oldest, has been mentioned by various writers;
but many of them, through ignorance or neglect, have not told
us that sea-water or brine was employed, as they speak in such
a manner as if any kind and even fresh water had been used
for that purpose.
Varro relates that he saw this process employed on the
Rhine1209. Pliny says1210 that oak timber had before been burnt for
that purpose. In another place he mentions a similar process
among the Gauls and the Germans1211, as Tacitus does among
the Hermanduri and the Catti1212. The former also states, on
the authority of Theophrastus, that the Umbri burnt salt in
the like manner1213. It is however certain that Pliny and other
ancient writers often quote from Theophrastus what, at present,
is not to be found in the works of that naturalist, but in
those of his preceptor Aristotle1214.
Pliny adds, that this paltry method of obtaining salt had
been long given up; and this indeed was the natural consequence
of increased civilization. It is however certain that
it was long continued in many countries, and in some still
exists.
About two centuries ago the inhabitants of the province
of Zeeland, descendants perhaps of the Catti, used no other
salt than what they obtained in the like manner, from mud
thrown up by the sea, which they burned and moistened with
sea-water, as we are told by Lemnius, who was himself a native
of that country. Boxhorn says, in his annotations on the
above-quoted passage of Tacitus, that he saw a painting at
Zirkzee, in which the whole process was represented. It is
probable that salt was boiled exactly in the same manner as
at some of the Sleswic islands, described by Denkwerth1215,
from whose account it is seen that the glebæ marinæ, of which
Lemnius speaks, consisted of mud mixed with roots growing
in them; and that the salt when afterwards refined was called
there Frisic, in all probability because the inhabitants had
learned to make it from their ancestors the Frieslanders. I
remember somewhere to have read that salt was made for a
long time in this manner by the so-called Wurst-Frieslanders,
in the country of Wurst, belonging to the duchy of Bremen.
The inhabitants also of the Austrian part of Moldavia, or
Buccowina as it is called, still use a salt, which they do not
boil, but burn with their superfluous wood, in the like manner
from the brine of a saline spring. A member of the former
Academy of Brussels1216 took the trouble to examine the
process as described by the ancients, and obtained, as might
certainly have been expected, a highly alkaline kind of common
salt, similar to that which Pliny, not without reason,
considered as a sort of nitrum, because undoubtedly it may
oftener have been an alkaline carbonate than common salt.
Boerhaave1217, in quoting the passages of the ancients, did
not reflect that, during the incineration of the wood, salt water
was poured over it. He considered the whole process as a
burning of potash, and thought that the salt obtained was fit
for use only because it was made according to the manner of
Tachenius. That indeed gives a carbonated salt, which is
almost saponaceous, and so mixed with various parts of the
burnt plants that it is much milder, consequently fitter for
use than common soda or pearlash can be; but that salt was
not so much of the Tachenian kind as a species of common
salt superabundant in alkali.
If the nitrum was carbonated alkali, there is reason to suppose
that the ancients must have occasionally mentioned in
their writings that it effervesced with acids. With the mineral
acids indeed they were not acquainted; but they had
vinegar, and that nitrum produced with this an effervescence
had been known in the oldest times. A very clear allusion
to this circumstance is found in the book of Proverbs, chap.
xxv. ver. 20; where Luther however translates the word by
chalk. Jerome, whose explanation I have already quoted,
was in some degree acquainted with this phænomenon; and
therefore to him the comparison of Solomon was intelligible1218.
But at present I can produce no proofs from Greek writers;
though they might have occurred during the use of nitrum
in medicine, in consequence of which it was often put into
vinegar.
We shall be further convinced what nitrum really was,
when the uses to which it was applied, as mentioned in the
works of the ancients, are considered. The most common, as
soap was not then known, appears to have been in washing, a
purpose for which our saltpetre would not be fit; besides, it
is at all times too scarce and too dear. I shall not here adduce
any proofs of its being employed in this manner, as they
often occur, and as several have been already given in the preceding
volume1219. Many salves and cosmetics were prepared
with nitrum; and in all probability articles of this kind, used
chiefly among the women, are to be understood by the term
nitron parthenicon, which occurs in Nicholas Myrepsius, in
the beginning of the fourteenth century; matronicon, mentioned
by the same, and by Alexander of Tralles, about the
year 565; and the nitrum matronale of Marcellus Empiricus,
in the fifth century. That the use of it for washing still continues
in the East, is confirmed in various books of travels.
The oldest glass, of the preparation of which any account
is to be found in history, was made by means of nitrum or
mineral alkali. For though I doubt that it could have been
produced on the sandy banks of the Belus, where some merchants,
when cooking, supported their pots with lumps of
nitrum1220, because sand is not so easily brought to a state of
fusion; it at any rate remains certain, that this supposed fusion
with our saltpetre is altogether impossible.
The use of nitrum for painting announces, without doubt,
an alkaline carbonate, and not saltpetre1221; and the case is the
same with the various uses in the cookery of the ancients,
many of which we have still retained. It was added to bread
in baking, according to Pliny1222, in the stead of salt, but probably
to promote its rising, for which purpose it is still employed
by the Egyptians, as potash was by our bakers. For
this use the mineral alkali was formerly brought from the
Levant to France, till it was declared by the physicians to be
injurious to the health1223.
When meat which was too fresh was to be dressed, it was
put into nitrum1224, in order to make it tender; and, according
to Forskäl and others, this is still practised in the East. Our
cooks also know that smoked meat, fish and other dried provisions
become more tender when placed in a ley of potash,
or when a little potash is added while they are boiling.
Nitrum, however, was employed for curing articles of food
which people wished to preserve. This appears to contradict
what has been mentioned above; but in all probability
a caustic sort was used for the former purpose; but for the
latter a mild kind, mixed with a great deal of common salt.
There were so many species, that some of them might have
been applied to quite contrary purposes.
As I conjecture, the use of nitrum for causing chestnuts
and other husky fruits to boil soft, was also known: to produce
the same effect, potash is at present thrown among boiling
lentils and peas. I am inclined to think that for this reason
Apicius caused chestnuts to be boiled with nitre.
It is highly probable that this effect of alkaline carbonates
induced agriculturists to believe that beans, peas, lentils and
other leguminous fruits, if steeped, before they were sown, in
water in which nitre had been dissolved, or if the dung spread
over the earth had been mixed with nitre, the future product
could be more easily boiled soft1225. However useful this addition
may be in cookery, it would produce little effect on seed;
and it appears to me that the old agriculturists placed little confidence
in the last-mentioned use, because they were not agreed
in regard to the result. Virgil and others seem to expect from
it an increase of the fruit1226; but others, security against beetles,
which eat the fruit and leave the husks empty1227. When cabbages
were transplanted they were strewed over with nitre, and
by these means were said to come sooner to maturity1228. Radishes
also were treated in the same manner, or besprinkled
with nitrous water, in order to make them more tender1229.
A common method employed by the ancient cooks to give
a beautiful green colour to pickled or boiled vegetables, was
to add nitrum to them while boiling; but this effect could be
produced by natrum, and not by the nitrum of the moderns,
or that neutral salt called saltpetre1230.
Among the oldest accounts of nitrum is that where it is
mentioned as being employed for embalming dead bodies.
It would be tiresome to read over and examine everything
written on that subject by the learned; but this much I think
is clear, that either the flesh, and in general the softer parts
of the body could be corroded in the course of seventy days
by the Egyptian nitrum1231, which, as above shown, was burnt,
and in general mixed with unslaked lime, and consequently
caustic1232; or that the moist parts could be desiccated by carbonate
alkali, in the same manner as the manufacturers of
parchment purify and dry their skins by the application of
chalk. That saltpetre in no case could be useful for this
purpose needs hardly be mentioned.
The ancient physicians, who were unacquainted with our
numerous class of salts, employed their nitrum in many ways,
and for a great variety of mixtures; but no writer, as far as
I know, ever took the trouble to examine these recipes, though
it has long since been declared that nitrum must have been
potash or salt of tartar. Matthioli1233 asserted, that those physicians
would act very improperly who should prescribe our
saltpetre where the ancients employed their nitrum; and indeed
those in the least acquainted with the effects of salts
must know, that all those extolled by the ancients announce
carbonated alkalies. Thus burnt nitrum was employed for
cleaning black teeth, as at present many use tobacco ashes
instead of tooth-powder. It is seen by the works of Aretæus
and others, that burnt nitrum was used as a caustic, till people
learned in modern times to prepare the more active causticum
potentiale, or sal causticum.
What the ancients say of the taste of their nitrum seems,
however, not entirely applicable to pure carbonated alkali;
and much less, or not at all, to our saltpetre. Had they
meant the latter, they would certainly not have failed to mention
the sensation of coolness which it occasions when applied
to the tongue. Galen and Aetius say, that nitrum is as bitter
as gall; but Serapio ascribes to it a saline taste, with a
small degree of bitterness; as does also Pliny, only that for
bitterness he substitutes the word sharpness. The names of
tastes, however, are as uncertain as the names of the colours
which occur in the works of the ancients. Both certainly deserve
to be more accurately examined, and to be defined by
comparing the things to which these names are given. Prosper
Alpinus, however, is of opinion that what the ancients
called amarum, is not inapplicable to the taste of natrum.
The ancients mention various springs and streams which
contained what they called nitrum1234; but nitrous water, according
to the present acceptation of the word, that is, water
which contains saltpetre, does not exist; and if credit is to be
given to Marggraf and others, that they observed traces of
saltpetre in some kinds of water, the instances must have been
so rare that mention of them could not be expected among
the ancients. Their nitrous water was undoubtedly alkaline,
and this indeed is not scarce. Such water was recommended
by the ancient physicians, both for bathing and drinking1235;
and Pliny says, it was singular that the salt of such water
would not shoot into crystals, like common salt, which is undoubtedly
true1236.
Alkaline water of this kind, such as that of Armenia, was
used for washing, and also by fullers. In Egypt, at present,
people wash in the same manner with nitrum.
It appears to me that many kinds of water, which were
only impure and not potable on account of their nauseous
taste, were considered by the ancients as nitrous. This seems
to be proved by the means which they propose for rendering
nitrous water fit to be drunk; that is, by throwing into it clay,
or some grains of barley1237. In the like manner, I saw the
brewers at Amsterdam improve their dirty water, in some
degree, by putting into it kneaded clay, and allowing it to
sink to the bottom.
One foundation more for my assertion may be found, I
think, in the name borax. The ancient nitrum by the Arabians
was called Bauracon or Baurach. When that salt,
which at present is everywhere called borax, became known
to the Arabians, it was at first generally considered as a kind
of nitre, and on that account called Baurach, because in most
of its properties it approached near to the nitrum of the ancients,
that is, the natrum of the present day. But afterwards,
when the difference became known, our borax, at least in
Europe, retained exclusively the general name of Baurach,
from which at length was formed the present word borax.
My conclusion therefore is, that the nitrum of the ancients
must have been mineral alkali; otherwise it is impossible
that our borax, which till modern times was reckoned to be
mineral alkali, should have been considered as a nitrum.
For many centuries past, the people in Africa and Asia,
and also in Spain and Sicily, have cultivated some kinds of
plants, which they dry and then burn to ashes. By regulating
the fire in a particular manner, they cause these ashes to assume
a certain degree of concretion, or vitrification, by which
means they are formed into solid cakes of a grey colour, interspersed
with many white and black spots. This substance,
which in consequence of the vitrification does not become
moist in the air, is broken into fragments, and sent to every
part of Europe under the name of soda, for the use of the
glass-houses, soap-boilers, dyers, and for other purposes.
These plants were undoubtedly first cultivated and employed
in Europe by the Arabians, who made known the use of them.
Those first or chiefly employed were named by them axnan,
usnan, usnen, or uscnanon; and also Hasciscio alcali, that is,
herba kali, the plant or herb kali, because the name kali, or,
with the article prefixed, al kali, was not given to the plant but
to the half-vitrified ashes kali. Hence the chemists call salts
obtained from the ashes of plants, alkaline salts. I do not
know how old this appellation may be; but it is to be found
in Vincent Bellovacensis and in the interpolated writings of
Geber and Avicenna, and particularly in a passage quoted by
the former from an old alchemist named Jahie, where it is
called sal alchali1238. All these salts formerly were considered
as nitrous salts, or a kind of nitrum. It was indeed soon observed
that soda and wood-ashes, which from the earliest
periods had been burnt in woody districts, and which are
now called potash, were not all of the same nature; but when
the difference between the mineral and vegetable alkalies began
to be studied, it was then known that soda contains the
former, that is, our natrum, and potash the latter, but both
indeed often rendered impure by earthy and foreign saline
particles; and that there are many plants from the ashes of
which mineral and not vegetable alkali is obtained. A question
now arises, How old in the Levant is the method of preparing
this natrum from the ashes of plants?
Michaelis is of opinion that it is mentioned in Malachi,
chap. iii. ver. 2; which passage I shall give according to
Luther’s translation: “Who shall stand when he appeareth?
for he is like the fire of the goldsmith, and the soap of the
scourer. He will sit and melt and purify the silver, and
make pure like gold and silver.” This learned man here
seems to think that the sacred writer alludes to refining the
noble metals, and that the word borith means soda, which indeed
may serve as a flux in the purification of them. I at
first considered this meaning as true; but, on closer examination,
I am fully convinced that we have both erred.
Those who read without prejudice the above passage of
Malachi, must remark, that a double comparison or double
image is employed. The messenger there promised was to
separate the good from the bad, the clean from the unclean.
The first occupation is compared with the labour of the gold-refiner;
the other, with that of the scourer of clothes. The
first image is afterwards heightened, because the poet, in all
probability, was desirous of applying the separation of the
ignoble parts, such as slag, by means of fire, as being the
stronger image which denotes punishment, in a closer manner
to the Levites and priests. At the time of the poet, before
the invention of soap, people employed for washing either
nitre or the saponaceous juice of certain plants, which I have
already endeavoured to determine. The borith of the washer
there expressly named, was undoubtedly one of these soap
plants, and not the half-vitrified ashes either of soda or
potash.
This passage of Malachi was so understood in the oldest
times. Professor Tychsen, a true pupil and intimate friend
of Michaelis, to whose opinion I subjected my doubts, assured
me that Michaelis was never able to convince him of the justness
of his exposition; especially as Jerome1239, without the least
hesitation, understood borith to be a plant growing in Palestine,
and used there for washing; and as the Greek translators,
who were much nearer to the period of the poet, and
could not be unacquainted with a thing so much used, have
translated borith by the word ποα, a plant.
In Jeremiah, chap. ii. ver. 221240, both the substances formerly
used for washing, nitrum and the soap-plant, are so clearly
named, that Michaelis was obliged to admit that we cannot
understand there soda or potash, but a ley or soap, the last
of which however was not at that time known. But, to speak
the truth, potash and soda would not be altogether unfit for
washing; at any rate, not less fit than the nether or nitrum
there named. What may serve, however, to refute entirely
the opinion of Michaelis is, that no proof has yet been found
that soda is of so great antiquity. For my part, I am acquainted
with no older mention of it than that which occurs
in the works of the more modern Arabian physicians, Avicenna,
Serapio, and others1241.
All these grounds afford sufficient proof that the nitrum of
the ancients was our natrum, and not our saltpetre. But still,
in the account given by the ancients of that salt, there remain
many things inexplicable. Thus, for example, no one can
accurately define the epithets, chalastricum, halmirhaga,
agrium, spuma nitri, aphronitrum, and others, because they
do not indicate different kinds, as already said, but accidental
properties of the same salt. Without enlarging further on
this subject, I shall only remark that Pliny admits a natural
and an artificial kind of nitrum, and this division is adopted
by Serapio; but the latter term has not the meaning which
we affix to it at present. The ancients were acquainted with
no other than native nitrum, which they called artificial
only when it required a little more trouble and art to obtain
it.
Most of the physicians recommend red nitrum, which is
mentioned also by many of the modern travellers. When
Prosper Alpinus was in Egypt the rose-red nitrum cost twice
as much as the white. The red colour, in all probability, arises
from a metallic admixture; yet the red nitrum may be purer
than the other, as red or violet rock-salt is often clearer and
purer than that which is colourless.
One of the darkest parts in the history of nitrum is the following
passage of Pliny: “Faciunt ex his vasa, nec non frequenter
liquatum cum sulphure, coquentes in carbonibus.” The latter
words he seems soon after to repeat: “Sal nitrum sulphuri
concoctum in lapidem vertitur.” From these words J. Rhodius1242
concludes that nitrum fixum was at that time known, because
he considered nitrum to be saltpetre; but in that case
with the sulphur, Glaser’s sal polychrest must properly have
been produced. This, however, was not the case, because
nitrum was fixed alkali. The ancients therefore, when they
placed it with sulphur in a crucible upon burning coals must
have obtained liver of sulphur, which when it cools is hard,
but soon becomes moist when exposed to the air. But I will
not venture to determine whether anything of this kind is to
be supposed in Pliny, who did not himself fully understand
the subject on which he touches.
The account of vessels made of nitrum is still more singular.
Michaelis conjectured1243 that articles of various kinds were cut
out of this substance, not for real use but merely for ornament,
in the same manner as similar things are cut out of rock-salt
in Transylvania, many specimens of which I have in my collection1244.
But even if nitrum had been compact and strong
enough for this purpose, there could not be the same inducement
to employ it as rock-salt, which, in consequence of its
solidity, transparency, brightness and smoothness, appears to
be capable of furnishing vessels equal to those made of the
most beautiful crystal. Dalechamp seems to explain the whole
as applicable to glazing; but in this case nitrum could serve
only as a flux.
Though it can be certainly proved that the nitrum of the ancients
was an alkaline salt, it is difficult to determine the time
when our saltpetre was discovered or made known. As many
have conjectured that it was a component part of the Greek
fire, invented about the year 678, which, in all probability,
gave rise to the invention of gunpowder, I examined the prescriptions
for the preparation of it. The oldest, and perhaps
the most certain, is that given by the princess Anna Comnena;
in which however I find only resin, sulphur and oil, but
not saltpetre. Klingenstierna1245 therefore judged very properly,
that all recipes in which saltpetre occurs are either
forged or of modern invention. Of this kind are those which
Scaliger, at least according to his own account, found in
Arabic works, and in which mention is made of oleum de nitro
and sal petræ1246. But it does not occur in that prescription
given by Marcus Græcus, and copied by Albertus Magnus,
who died in 12801247.
I must still believe that the first certain mention of saltpetre
will be found in the oldest account of the preparation of
gunpowder, which, in my opinion, became known in Europe
in the thirteenth century, about the same time that the use of
the Greek fire, of which there were many kinds, began to be
lost. Among the oldest information on this subject is that
found in the above-quoted work of Albertus Magnus, and the
writings of Roger Bacon, who died in 1278. It is doubted
whether the first-mentioned treatise belongs to Albertus; but
it is certain that the author, whoever he may have been, and
also Bacon, both derived their information from the same
source.
When M. von Arretin lately announced that he was about
to publish a manuscript preserved in the electoral library at
Munich, which contained the true recipe for making the
Greek fire and the oldest for gunpowder, the same writing,
as appears, was printed from two manuscripts in the library
at Paris. I have now before me a copy of it, which was
transmitted to the library of our university by M. Laporte
Dutheil, conservateur des Manuscrits de la Bibliothèque1248.
It contains many recipes, but only with a few variations,
as in Albertus Magnus; and it may be evidently seen that
Roger Bacon employed this writing, which is mentioned by
Jebb in the preface to his edition, from a copy preserved in
the library of Dr. Mead. Of this Marcus Græcus nothing at
present is known. According to some, he lived in the ninth
century; but others, with more probability, place him in the
thirteenth. Of his work, perhaps, we have only a translation;
for, from the surname Græcus, there is reason to think that
the original was written in the Greek language. I must,
however, remark that Cardan, where he gives directions for
making a fire which can be kindled by water, names Marcus
Gracchus, but not Græcus. Scaliger, who, as is very probable,
had this writing also, makes no mention of it or its
author.
This Marcus speaks of saltpetre three times; first under
the name of sal petrosum, which occurs also in the same prescription
in Albertus Magnus; but the addition, which Albertus
does not repeat, is very remarkable. In my opinion, scrophulæ
contra lapides means the incrustation found on walls,
which was represented as a kind of leprosy. The addition of
ashes, or alkaline salts, the author either forgot or omitted,
because perhaps he did not consider it as indispensably necessary.
In another place it is said, Lapis qui dicitur petra solis,
or, as it is in other manuscripts, salis; but whether saltpetre
is here understood I will not venture to determine. In a
third passage we find the words de sale petroso, or de salepetro.
In the works of Bacon the term sal petræ occurs at least
three times. According to Casiri, the term pulvis nitratus is
to be found in an Arabic manuscript, the author of which
lived about the year 12491249. If the work of Geber, already
quoted, be genuine, and if this writer lived, as some think, in
the eighth century, it would be the oldest where saltpetre is
mentioned, in a prescription for an aqua solutiva or dissolutiva,
which almost seems to be aqua regia. I have not observed
the name sal petræ in the works of Vincent Bellovacensis,
who lived in the thirteenth century.
In a word, I am more than ever inclined to accede to the
opinion of those who believe that gunpowder was invented in
India, and brought by the Saracens from Africa to the Europeans,
who however improved the preparation of it, and
found out different ways of employing it in war, as well as
small arms and cannon1250. In no country could saltpetre, and
the various uses of it, be more easily discovered than in India,
where the soil is so rich in nitrous particles that nothing is
necessary but to lixiviate it in order to obtain saltpetre; and
where this substance is so abundant, that almost all the gunpowder
used in the different wars with which the sovereigns
of Europe have tormented mankind was made from Indian
saltpetre1251. If it be true that saltpetre was not known in
Europe till the thirteenth century, neither gunpowder nor
aquafortis could have been made before that time; for the
former cannot be prepared without saltpetre, nor the latter
without nitre. But if it be true that this salt was known at
a much earlier period in India, it is not improbable that both
gunpowder and aquafortis were used by the Indians and the
Arabians before they were employed by the Europeans, especially
as the former were the first teachers of chemistry to the
latter. In my opinion, what I have already related proves
this in regard to gunpowder; and what I shall here add will
afford an equal proof in regard to aquafortis.
It is difficult to discover the first mention of mineral acids
in the writings of the ancient chemists. In the course of
their numerous experiments they obtained indeed, at an early
period, acids, the utility of which they extol; but each concealed
the process by which they were made; and as they
had no method of obtaining them pure, they were for a long
time unacquainted with the difference between the kinds.
Their prescriptions, when they are found, are so contradictory
and so carelessly written, that it is almost impossible to conjecture
which of the known acids forms the principal component
parts in their recipes or mixtures.
It appears to me, that the first intelligible account of aquafortis
occurs in the writings of the Arabians, or of the pupils
of Arabian chemists. At present I am acquainted with none
older than that to be found in the works of Geber. For
though I do not believe that those of which we have Latin
translations belong to a Geber of the eighth or ninth century,
I am ready to admit that they may be, at any rate, of the
twelfth. This appears probable, because about that period
aquafortis and various arts are oftener mentioned, and in a
much clearer manner, in these writings.
It is to be regretted in the history of chemistry, that it is
impossible to determine the period of the Greek chemist or
alchemist known under the name of Synesius; but it cannot
be doubted that he borrowed a great deal from the works of
the Arabians. This Synesius, among the chemical solvents,
mentions water of saltpetre, which might be considered as
aquafortis1252. But, as he mentions at the same time aqua fæcis,
he appears to me to allude to the nitrum of the ancients, not
to our saltpetre, and in general to strong alkaline leys, which
indeed are capable of dissolving many bodies.
The monk Theophilus, of whom I have already spoken,
and who in all probability lived in the twelfth century, appears
also to have been acquainted with aquafortis; for in
some of the passages quoted from his works by Raspe1253, he
speaks of an acid which dissolved all metals. In the writings
of Vincent Bellovacensis, in the thirteenth century, some
traces, but very doubtful, are found of aquafortis. Where
he mentions the different sorts of gold he speaks of dissolving
it, but by this expression he does not allude to its treatment
with fire, which he speaks of separately1254. In another place
he mentions the different solvents, and among these names
vegetable acids, a water of sal-ammoniac, and a water obtained
from alum by distillation. He here means undoubtedly
a mineral acid1255. Michael Meier, the most learned chemist
of the seventeenth century, says that Vincentius speaks
of aquafortis as of a secret; but the passage I have not yet
been able to find1256.
Spielman states that Lullius, who died in 1315, in the
eightieth year of his age, gave an account of his obtaining
aquafortis from saltpetre by the addition of vitriol, and that
Basilius Valentin was acquainted with the use of clay for the
same purpose. Picus Mirandula however declares it to be
uncertain whether Arnoldus de Villa Nova was acquainted
with the acid of saltpetre in the fourteenth century.
It appears to be an old tradition that this acid was first
employed at Venice, by some Germans, for separating the
noble metals, and conveyed thence as an article of merchandize
to every part of Europe. The persons who prepared it
were there narrowly watched, in order that the process might
not become known. They were employed chiefly for separating
the gold from the Spanish silver, and by these means
acquired great riches. Hence arose the report that the
people of Venice understood the art of making gold; and it
is certain that in many countries the gold refiners were for a
long time considered as gold makers; but in no period were
there more gold makers than in that when separation in the
moist way became known. I can however give less account
of this art of the Venetians than of the introduction of it into
France in the fifteenth or the beginning of the sixteenth
century.
William Budæus, who was born in 1467, and died in 1540,
speaks of it in his book, printed for the first time in 1516, as
a thing entirely new at that period1257. A man of low extraction,
named Le Cointe, first undertook to separate gold
from silver at Paris, by means of a water which Budæus calls
aqua chrysulca. It is very remarkable, that by means of this
water he could separate the smallest particle of gold from
silver, and from every other metal; nay, he could even take
from vessels their gilding without altering their form. By
this art he acquired great wealth; which together with his
secret descended to his son, who at the time was the only
gold refiner at Paris.
He adds, that the art was exceedingly dangerous as well
as unhealthy, and required great precaution. The possessor
of it, when he became rich, left the execution of the work to
a servant, whom he directed at a distance, that he might not
expose himself to the pernicious fumes of the effervescing
liquor. The fumes of the acid derived from saltpetre are
indeed prejudicial to the health; but the danger has been
much exaggerated, and no doubt with a view to deter people
from attempting to discover the art, and to furnish a pretence
for raising the price of the production1258.
Budæus relates also, that the gold was left behind undissolved.
The silver only was dissolved, and by another art
was separated from the water and washed. It may here be
easily perceived that Le Cointe employed aquafortis; but if
he was able to loosen the gold from gilt vessels without destroying
them, he must have used aqua regia, which consequently
was not then unknown.
From other information, it appears that the mint at Paris
purchased the art from Le Cointe’s son, but still kept it a
secret. On this account Francis I., by a decree issued at
Blois on the 19th of March 1540, authorized the raising the
value of coin, in order to defray the expense of fuel and
assaying-water. In the middle of the seventeenth century,
the preparation of aquafortis and the process of assaying in
the moist way were fully known in France. At any rate, in
the month of January 1637, the distillers obtained a guild
letter, in which aquafortis is mentioned among the articles
sold by them.
When saltpetre became necessary to governments for the
manufacture of gunpowder, they endeavoured to obtain it at
as cheap a rate as possible. No one before suspected that
rulers would be justified in exclusively carrying away the incrustation
of walls from private houses, which, when it could
be used, became accessorium fundi. But the idea of regalia,
so often abused, was extended so wide under various pretences,
that the saltpetre regale and the letting of it was one
of the severest oppressions to which the people were exposed
by their rulers, and which occasioned almost as bitter complaints
as the hunting regale, founded on no better grounds.
I shall not here attempt to delineate the sufferings which were
thus occasioned in many countries; they are still fresh in
remembrance.
The oldest mention of this hated regale which I myself
have found is of the year 1419. At that time, Gunther,
archbishop of Magdeburg, granted to some person the right
of searching out saltpetre and boiling it, during a year, in the
district of Gibichenstein, for which he was to pay a barrel of
saltpetre, and deliver to the archbishop the remainder at the
rate of five cross-groschens per pound. The succeeding
archbishop, Frederick, let in the year 1460, to a burgher of
Halle, all the earth and the saltpetre that could be collected
from it in the bailiwick of Gibichenstein, for four years, at
the annual rent of a barrel of good refined saltpetre. On the
same conditions, bishop Ernest, in 1477, let to some one for
his lifetime the collection of the saltpetre. In 1544, a certain
person obtained the collection of saltpetre from two
heaps of rubbish before the gates at Halle. The magistrates
of Halle also in 1545 had a saltpetre-work and a powder-mill.
In the year 1560, John VI., archbishop of Triers, gave to
some one permission to search for and dig up saltpetre. In
1583, the saltpetre regale was confirmed by a Brandenburg
decree as a thing long known, and the case was the same
with a Hessian of the year 1589.
It is very probable that this example was soon followed by
most sovereigns; but even if they had collected and scraped
together the nitrous incrustation of all the walls in Europe,
they certainly would not have found a quantity of saltpetre
sufficient for the gunpowder used in the numerous wars
which took place, had not a much greater supply been obtained
from India, and particularly from Patna. I do not
know whether the Portuguese brought this article to Europe;
but that it was imported at a very early period by the Dutch
is proved by the oldest ladings of their return ships; and
they at length found means to appropriate this branch of
trade so entirely to themselves, that the other Europeans for
a long time could not obtain any saltpetre in India.
In the seventeenth century, when chemistry began to be
studied with more care and attention in Europe, and particularly
in Germany, and the component parts and production
of saltpetre became better known, many conceived the
idea of improving the methods of obtaining it in Europe so
much, that it might be possible to dispense with the Indian
saltpetre, and flattered themselves with the hopes of thence
deriving great advantages. Some proposed to fill tubes with
putrifiable substances and earth capable of fixing of the nitric
acid; others preferred building vaults of these substances, and
Glauber recommended the filling of pits with them. The
proposal, however, which met with the greatest approbation
was that of building walls of them. Through a confidence
in this idea, towns and villages were compelled to erect and
maintain a certain number of saltpetre walls, under the most
gracious promise that the collectors of saltpetre should no
longer be allowed to spoil private dwellings, or render them
unhealthful.
But experience has shown that all the means and coercive
measures hitherto employed have rendered the European saltpetre
much dearer than that obtained by commerce from
Bengal. This will be readily comprehended, when it is
known that earth richly impregnated with saltpetre abounds
in India, and that it may be extracted by lixiviation without
any addition, and brought to crystallize in that warm climate
without the aid of fire; that the price of labour there is exceedingly
low; that this salt is brought from India instead
of ballast by all the commercial nations of Europe, where the
competition of the sellers prevents the price from ever being
extravagantly high, while the preparation of it in Europe, in
consequence of the still increasing price of labour, fuel and
ashes, is always becoming dearer. This regale will at length
be everywhere scouted. In the duchy of Wurtemberg and
the Prussian states, where it was most rigidly enforced, in
consequence of an urgent representation from the States it
was abolished in 1798; but in both countries an indemnification
was given to government for the loss. The case also
has been the same in Sweden1259. In the duchy of Brunswick
it was soon suffered to drop; but in the electoral dominions
it never was introduced.
[The greater part of our nitre is derived from Bengal,
where, as in Egypt, Persia, Spain, &c., it exists in the soil.
It is separated by lixiviation and crystallization. In France,
Sweden and some other countries it is prepared artificially in
nitre-beds. These are formed of various animal matters,
mixed with lime or mortar-rubbish; the mixture is watered
and stirred occasionally, and allowed to remain for
a considerable time. The whole is then lixiviated and decomposed
by carbonate of potash. The nitre is then separated
and purified by crystallization. In some cases wood-ashes
are mixed with the animal matters; the decomposition
with potash is then unnecessary.
It is a question whether the nitric acid in the nitre arises
from the nitrogen of the atmosphere or that in the animal
matters. Dr. Davy has found nitre in a cave at Ceylon,
where no nitrogenous matter was present; and in some parts
of India, Spain, and some other countries, at a distance from
all habitations, immense quantities of nitre are reproduced in
soils which have been washed the year before. Nitre is
directly brought into this country from Calcutta and Madras,
in bags containing from 150 lbs. to 175 lbs. each. From
200,000 cwts. to 260,000 cwts. are annually imported into
the United Kingdom.
In making gunpowder, the components, the sulphur, nitre,
and charcoal should be as pure as possible, and reduced to
the finest possible powder; they are sifted and mixed in
the proper proportions. The mixture is then made into a
cake with water, and ground between calcareous millstones.
It is then granulated through sieves in another mill, and
again sifted. It is then polished and hardened by revolving
rapidly in a cask, and finally dried. The proportions of
the constituents vary in different countries; at Waltham
Abbey they are seventy-five nitre, fifteen charcoal and ten
sulphur. The quantity of gunpowder consumed in this country
is enormous; moreover, 4,000,000 lbs. are annually exported,
the greater part of which is sent to the western coast
of Africa.
The force of the explosion of gunpowder is owing to the
sudden disengagement of gaseous products; these consist of
nitrogen, carbonic oxide, carbonic acid, and sulphurous acid
gases; and their volume has been calculated to amount to
2000 times the bulk of the powder.]